A neutral low-coordinate heterocyclic bismuth-tin species

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dc.bibliographicCitation.firstPage13834eng
dc.bibliographicCitation.issue72eng
dc.bibliographicCitation.lastPage13837eng
dc.bibliographicCitation.volume51eng
dc.contributor.authorHering-Junghans, C.
dc.contributor.authorSchulz, A.
dc.contributor.authorVillinger, A.
dc.date.accessioned2022-06-24T06:07:29Z
dc.date.available2022-06-24T06:07:29Z
dc.date.issued2015
dc.description.abstractThe reaction of distannadiazane bearing bulky RAr*-groups (RAr* = C6H2{C(H)Ph2}2R-2,6,4; R = iPr, tBu) with ECl3 (E = Sb, Bi) was studied resulting in the isolation of previously unknown N,N-bis(dichloropnictino)amines (3) and a novel heterocyclic carbenoid bismuth species (4) bearing a Bi(III) and a Sn(IV) center. The structure and bonding was investigated by means of X-ray structure elucidations and DFT calculations.eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/9258
dc.identifier.urihttps://doi.org/10.34657/8296
dc.language.isoengeng
dc.publisherCambridge : Soc.eng
dc.relation.doihttps://doi.org/10.1039/c5cc04516a
dc.relation.essn1364-548X
dc.relation.ispartofseriesChemical communications : ChemComm 51 (2015), Nr. 72eng
dc.rights.licenseCC BY 3.0 Unportedeng
dc.rights.urihttps://creativecommons.org/licenses/by/3.0/eng
dc.subjectbismutheng
dc.subjectheterocyclic compoundeng
dc.subjecttineng
dc.subjectcalculationeng
dc.subjectcarbon nuclear magnetic resonanceeng
dc.subjectchemical structureeng
dc.subjectcomparative studyeng
dc.subjectcrystaleng
dc.subjectfiltrationeng
dc.subjectproton nuclear magnetic resonanceeng
dc.subjectsynthesiseng
dc.subject.ddc540eng
dc.titleA neutral low-coordinate heterocyclic bismuth-tin specieseng
dc.typearticleeng
dc.typeTexteng
dcterms.bibliographicCitation.journalTitleChemical communications : ChemCommeng
tib.accessRightsopenAccesseng
wgl.contributorLIKATeng
wgl.subjectChemieeng
wgl.typeZeitschriftenartikeleng
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