Mechanochemistry-assisted synthesis of hierarchical porous carbons applied as supercapacitors
dc.bibliographicCitation.firstPage | 1332 | eng |
dc.bibliographicCitation.journalTitle | Beilstein Journal of Organic Chemistry | eng |
dc.bibliographicCitation.lastPage | 1341 | eng |
dc.bibliographicCitation.volume | 13 | |
dc.contributor.author | Leistenschneider, Desirée | |
dc.contributor.author | Jäckel, Nicolas | |
dc.contributor.author | Hippauf, Felix | |
dc.contributor.author | Presser, Volker | |
dc.contributor.author | Borchardt, Lars | |
dc.date.accessioned | 2018-04-04T09:13:11Z | |
dc.date.available | 2019-06-28T13:59:45Z | |
dc.date.issued | 2017 | |
dc.description.abstract | A solvent-free synthesis of hierarchical porous carbons is conducted by a facile and fast mechanochemical reaction in a ball mill. By means of a mechanochemical ball-milling approach, we obtained titanium(IV) citrate-based polymers, which have been processed via high temperature chlorine treatment to hierarchical porous carbons with a high specific surface area of up to 1814 m2 g−1 and well-defined pore structures. The carbons are applied as electrode materials in electric double-layer capacitors showing high specific capacitances with 98 F g−1 in organic and 138 F g−1 in an ionic liquid electrolyte as well as good rate capabilities, maintaining 87% of the initial capacitance with 1 M TEA-BF4 in acetonitrile (ACN) and 81% at 10 A g−1 in EMIM-BF4. | eng |
dc.description.version | publishedVersion | eng |
dc.format | application/pdf | |
dc.identifier.uri | https://doi.org/10.34657/5101 | |
dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/4652 | |
dc.language.iso | eng | eng |
dc.publisher | Frankfurt, M. : Beilstein-Institut zur Förderung der Chemischen Wissenschaften | eng |
dc.relation.doi | https://doi.org/10.3762/bjoc.13.130 | |
dc.rights.license | CC BY 4.0 Unported | eng |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | eng |
dc.subject.ddc | 620 | eng |
dc.subject.other | electrochemical energy storage | eng |
dc.subject.other | mesoporous | eng |
dc.subject.other | microporous | eng |
dc.subject.other | solvent-free | eng |
dc.subject.other | supercapacitor | eng |
dc.subject.other | templated carbon | eng |
dc.title | Mechanochemistry-assisted synthesis of hierarchical porous carbons applied as supercapacitors | eng |
dc.type | Article | eng |
dc.type | Text | eng |
tib.accessRights | openAccess | eng |
wgl.contributor | INM | eng |
wgl.subject | Ingenieurwissenschaften | eng |
wgl.subject | Umweltwissenschaften | eng |
wgl.type | Zeitschriftenartikel | eng |
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