(Cyanido-κC)(2,2-diphenylacetamido-κ2 N,O)bis(η5-pentamethylcyclopentadienyl)zirconium(IV)
| dc.bibliographicCitation.issue | 2 | |
| dc.bibliographicCitation.journalTitle | Acta Crystallographica Section E: Structure Reports Online | eng |
| dc.bibliographicCitation.volume | 70 | eng |
| dc.contributor.author | Becker, L. | |
| dc.contributor.author | Spannenberg, A. | |
| dc.contributor.author | Arndt, P. | |
| dc.contributor.author | Rosenthal, U. | |
| dc.date.accessioned | 2020-09-06T07:58:32Z | |
| dc.date.available | 2020-09-06T07:58:32Z | |
| dc.date.issued | 2014 | |
| dc.description.abstract | In the title compound, [Zr(C10H15)2(C14H12NO)(CN)], the ZrIV atom is coordinated by two pentamethylcyclopentadienyl ligands, the amidate ligand via the N and O atoms, and an additional C N ligand. The four-membered metallacycle is nearly planar (r.m.s. deviation = 0.008Å). In the crystal, the molecules are connected into centrosymmetric dimers via pairs of N - HN hydrogen bonds. | eng |
| dc.description.version | publishedVersion | eng |
| dc.identifier.uri | https://doi.org/10.34657/4196 | |
| dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/5567 | |
| dc.language.iso | eng | eng |
| dc.publisher | Chester : International Union of Crystallography | eng |
| dc.relation.doi | https://doi.org/10.1107/S1600536814001160 | |
| dc.relation.issn | 1600-5368 | |
| dc.rights.license | CC BY 4.0 Unported | eng |
| dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | eng |
| dc.subject.ddc | 540 | eng |
| dc.subject.other | data-to-parameter ratio = 17.9 | eng |
| dc.subject.other | mean σ(C-C) = 0.003 Å | eng |
| dc.subject.other | R factor = 0.033 | eng |
| dc.subject.other | single-crystal X-ray study | eng |
| dc.subject.other | T = 150 K | eng |
| dc.subject.other | wR factor = 0.085 | eng |
| dc.title | (Cyanido-κC)(2,2-diphenylacetamido-κ2 N,O)bis(η5-pentamethylcyclopentadienyl)zirconium(IV) | eng |
| dc.type | Article | eng |
| dc.type | Text | eng |
| tib.accessRights | openAccess | eng |
| wgl.contributor | LIKAT | eng |
| wgl.subject | Chemie | eng |
| wgl.type | Zeitschriftenartikel | eng |