Ultrafast structural and vibrational dynamics of the hydration shell around DNA

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Date

Volume

41

Issue

Journal

EPJ Web of Conferences

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Book Title

Publisher

Les Ulis : EDP Sciences

Abstract

Two-dimensional infrared spectroscopy in the frequency range of OH- and NH stretch excitations serves for a direct mapping of hydration dynamics around DNA. A moderate slowing down of structural dynamics and resonant OH stretch energy transfer is observed in the DNA water shell compared to bulk water.

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CC BY-NC 2.0 Unported