Delayed relaxation of highly excited naphthalene cations
dc.bibliographicCitation.firstPage | 72044 | eng |
dc.bibliographicCitation.issue | 7 | eng |
dc.bibliographicCitation.journalTitle | Journal of physics: Conference Series | eng |
dc.bibliographicCitation.volume | 1412 | eng |
dc.contributor.author | Reitsma, G. | |
dc.contributor.author | Hummert, J. | |
dc.contributor.author | Dura, J. | |
dc.contributor.author | Loriot, V. | |
dc.contributor.author | Vrakking, M.J.J. | |
dc.contributor.author | Lépine, F. | |
dc.contributor.author | Kornilov, O. | |
dc.date.accessioned | 2021-11-18T09:57:34Z | |
dc.date.available | 2021-11-18T09:57:34Z | |
dc.date.issued | 2020 | |
dc.description.abstract | The efficiency of energy transfer in ultrafast electronic relaxation of molecules depends strongly on the complex interplay between electronic and nuclear motion. In this study we use wavelength-selected XUV pulses to induce relaxation dynamics of highly excited cationic states of naphthalene. Surprisingly, the observed relaxation lifetimes increase with the cationic excitation energy. We propose that this is a manifestation of a quantum mechanical population trapping that leads to delayed relaxation of molecules in the regions with a high density of excited states. © 2019 Published under licence by IOP Publishing Ltd. | eng |
dc.description.version | publishedVersion | eng |
dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/7344 | |
dc.identifier.uri | https://doi.org/10.34657/6391 | |
dc.language.iso | eng | eng |
dc.publisher | Bristol : IOP Publ. | eng |
dc.relation.doi | https://doi.org/10.1088/1742-6596/1412/7/072044 | |
dc.relation.essn | 1742-6596 | |
dc.rights.license | CC BY 3.0 Unported | eng |
dc.rights.uri | https://creativecommons.org/licenses/by/3.0/ | eng |
dc.subject.ddc | 530 | eng |
dc.subject.other | energy transfer | eng |
dc.subject.other | electronic relaxation of molecules | eng |
dc.subject.other | cationic excitation energy | eng |
dc.title | Delayed relaxation of highly excited naphthalene cations | eng |
dc.type | Article | eng |
dc.type | Text | eng |
tib.accessRights | openAccess | eng |
wgl.contributor | MBI | eng |
wgl.subject | Physik | eng |
wgl.type | Zeitschriftenartikel | eng |
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