Flux Growth and Characterization of Bulk InVO4 Crystals

Simple item page
dc.bibliographicCitation.articleNumber1439
dc.bibliographicCitation.firstPage1439
dc.bibliographicCitation.issue10
dc.bibliographicCitation.journalTitleCrystalseng
dc.bibliographicCitation.volume13
dc.contributor.authorVoloshyna, Olesia
dc.contributor.authorGorbunov, Mikhail V.
dc.contributor.authorMikhailova, Daria
dc.contributor.authorMaljuk, Andrey
dc.contributor.authorSeiro, Silvia
dc.contributor.authorBüchner, Bernd
dc.date.accessioned2024-05-10T05:38:28Z
dc.date.available2024-05-10T05:38:28Z
dc.date.issued2023
dc.description.abstractThe flux growth of InVO4 bulk single crystals has been explored for the first time. The reported eutectic composition at a ratio of V2O5:InVO4 = 1:1 could not be used as a self-flux since no sign of melting was observed up to 1100 °C. Crystals of InVO4 of typical size 0.5 × 1 × 7 mm3 were obtained using copper pyrovanadate (Cu2V2O7) as a flux, using Pt crucibles. X-ray powder diffraction confirmed the orthorhombic Cmcm structure. Rests of the flux material were observed on the sample surface, with occasional traces of Pt indicating some level of reaction with the crucible. X-ray absorption spectroscopy showed that oxidation states of indium and vanadium ions are +3 and +5, respectively. The size and high quality of the obtained InVO4 crystals makes them excellent candidates for further study of their physical properties.eng
dc.description.fondsLeibniz_Fonds
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/14613
dc.identifier.urihttps://doi.org/10.34657/13644
dc.language.isoeng
dc.publisherBasel : MDPI
dc.relation.doihttps://doi.org/10.3390/cryst13101439
dc.relation.essn2073-4352
dc.rights.licenseCC BY 4.0 Unported
dc.rights.urihttps://creativecommons.org/licenses/by/4.0
dc.subject.ddc540
dc.subject.otherEXAFS (extended X-ray absorption fine structure)eng
dc.subject.otherflux growtheng
dc.subject.otherindium vanadateeng
dc.subject.otherXANES (X-ray absorption near-edge spectroscopy)eng
dc.titleFlux Growth and Characterization of Bulk InVO4 Crystalseng
dc.typeArticleeng
dc.typeTexteng
tib.accessRightsopenAccess
wgl.contributorIFWD
wgl.subjectChemieger
wgl.typeZeitschriftenartikelger
Files
Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
crystals-13-01439.pdf
Size:
3.97 MB
Format:
Adobe Portable Document Format
Description:
Download
Collections
Chemie