(+)-Chlorido[(1,2,3,4-η;P 2′)-2′- diphenylphosphanyl-2-diphenylphosphoryl-1,1′-binaphthyl]rhodium(I) methanol monosolvate
| dc.bibliographicCitation.issue | 3 | |
| dc.bibliographicCitation.volume | 68 | eng |
| dc.contributor.author | Meissner, A. | |
| dc.contributor.author | Selle, C. | |
| dc.contributor.author | Drexler, H.-J. | |
| dc.contributor.author | Heller, D. | |
| dc.date.accessioned | 2020-09-06T07:58:36Z | |
| dc.date.available | 2020-09-06T07:58:36Z | |
| dc.date.issued | 2012 | |
| dc.description.abstract | In the title complex, [RhCl(C 44H 32OP 2)]·CH 3OH, the Rh I ion is coordinated by a naphthyl group of a partially oxidized 2,2′-bis-(diphenylphosphanyl)-1, 1′-binaphthyl (BINAP) ligand in a 4 mode, one P atom of the diphenylphosphanyl group and one Cl atom. The P=O group does not interact with the Rh I ion but accepts an O - H⋯O hydrogen bond from the methanol solvent molecule. | eng |
| dc.description.version | publishedVersion | eng |
| dc.identifier.uri | https://doi.org/10.34657/4203 | |
| dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/5574 | |
| dc.language.iso | eng | eng |
| dc.publisher | Chester : International Union of Crystallography | eng |
| dc.relation.doi | https://doi.org/10.1107/S1600536812003418 | |
| dc.relation.ispartofseries | Acta Crystallographica Section E: Structure Reports Online 68 (2012), 3 | eng |
| dc.relation.issn | 1600-5368 | |
| dc.rights.license | CC BY 4.0 Unported | eng |
| dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | eng |
| dc.subject | data-to-parameter ratio = 13.5 | eng |
| dc.subject | mean σ(C-C) = 0.006 Å | eng |
| dc.subject | R factor = 0.027 | eng |
| dc.subject | single-crystal X-ray study | eng |
| dc.subject | T = 200 K | eng |
| dc.subject | wR factor = 0.043 | eng |
| dc.subject.ddc | 540 | eng |
| dc.title | (+)-Chlorido[(1,2,3,4-η;P 2′)-2′- diphenylphosphanyl-2-diphenylphosphoryl-1,1′-binaphthyl]rhodium(I) methanol monosolvate | eng |
| dc.type | article | eng |
| dc.type | Text | eng |
| dcterms.bibliographicCitation.journalTitle | Acta Crystallographica Section E: Structure Reports Online | eng |
| tib.accessRights | openAccess | eng |
| wgl.contributor | LIKAT | eng |
| wgl.subject | Chemie | eng |
| wgl.type | Zeitschriftenartikel | eng |