Synthesis of C2-Symmetric Diphosphormonoamidites and Their Use as Ligands in Rh-Catalyzed Hydroformylation: Relationships between Activity and Hydrolysis Stability

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dc.bibliographicCitation.firstPage247
dc.bibliographicCitation.issue2
dc.bibliographicCitation.lastPage253
dc.bibliographicCitation.volume6
dc.contributor.authorMorales Torres, Galina
dc.contributor.authorBehrens, Stephan
dc.contributor.authorMichalik, Dirk
dc.contributor.authorSelent, Detlef
dc.contributor.authorSpannenberg, Anke
dc.contributor.authorLühr, Susan
dc.contributor.authorDyballa, Katrin Marie
dc.contributor.authorFranke, Robert
dc.contributor.authorBörner, Armin
dc.date.accessioned2023-01-19T09:43:51Z
dc.date.available2023-01-19T09:43:51Z
dc.date.issued2017-1-23
dc.description.abstractA series of diphosphoramidites has been synthetized with a piperazine, homopiperazine, and an acyclic 1,2-diamine unit in the backbone. New compounds were tested alongside related N-acyl phosphoramidites as ligands in the Rh-catalyzed hydroformylation of n-octenes to investigate their influence on the activity and regioselectivity. A subsequent study of their hydrolysis stability revealed that the most stable ligands induced the highest activity in the catalytic reaction.eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/10936
dc.identifier.urihttp://dx.doi.org/10.34657/9962
dc.language.isoeng
dc.publisherWeinheim : Wiley-VCH-Verl.
dc.relation.doihttps://doi.org/10.1002/open.201600152
dc.relation.essn2191-1363
dc.relation.ispartofseriesChemistryOpen 6 (2017), Nr. 2
dc.rights.licenseCC BY-NC-ND 4.0 Unported
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectdiphosphoramiditeseng
dc.subjecthydroformylationeng
dc.subjectregioselectivityeng
dc.subjectrhodiumeng
dc.subjectstructure–activity relationshipseng
dc.subject.ddc540
dc.titleSynthesis of C2-Symmetric Diphosphormonoamidites and Their Use as Ligands in Rh-Catalyzed Hydroformylation: Relationships between Activity and Hydrolysis Stabilityeng
dc.typearticleeng
dc.typeTexteng
dcterms.bibliographicCitation.journalTitleChemistryOpen
tib.accessRightsopenAccesseng
wgl.contributorLIKAT
wgl.subjectChemieger
wgl.typeZeitschriftenartikelger
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