Efficient methylation of anilines with methanol catalysed by cyclometalated ruthenium complexes
dc.bibliographicCitation.firstPage | 2512 | eng |
dc.bibliographicCitation.issue | 7 | eng |
dc.bibliographicCitation.journalTitle | Catalysis Science & Technology | eng |
dc.bibliographicCitation.lastPage | 2517 | eng |
dc.bibliographicCitation.volume | 11 | eng |
dc.contributor.author | Piehl, Patrick | |
dc.contributor.author | Amuso, Roberta | |
dc.contributor.author | Spannenberg, Anke | |
dc.contributor.author | Gabriele, Bartolo | |
dc.contributor.author | Neumann, Helfried | |
dc.contributor.author | Beller, Matthias | |
dc.date.accessioned | 2022-03-25T07:24:45Z | |
dc.date.available | 2022-03-25T07:24:45Z | |
dc.date.issued | 2021 | |
dc.description.abstract | Cyclometalated ruthenium complexes4-10allow the effective methylation of anilines with methanol to selectively giveN-methylanilines. This hydrogen autotransfer procedure proceeds under mild conditions (60 °C) in a practical manner (NaOH as base). Mechanistic investigations suggest an active homogenous ruthenium complex and β-hydride elimination of methanol as the rate determining step. © The Royal Society of Chemistry 2021. | eng |
dc.description.version | publishedVersion | eng |
dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/8376 | |
dc.identifier.uri | https://doi.org/10.34657/7414 | |
dc.language.iso | eng | eng |
dc.publisher | London : RSC Publ. | eng |
dc.relation.doi | https://doi.org/10.1039/d0cy02210a | |
dc.relation.essn | 2044-4761 | |
dc.relation.issn | 2044-4753 | |
dc.rights.license | CC BY-NC 3.0 Unported | eng |
dc.rights.uri | https://creativecommons.org/licenses/by-nc/3.0/ | eng |
dc.subject.ddc | 540 | eng |
dc.subject.other | Alkylation | eng |
dc.subject.other | Aniline | eng |
dc.subject.other | Methanol | eng |
dc.subject.other | Methylation | eng |
dc.subject.other | Sodium hydroxide | eng |
dc.subject.other | Auto-transfer | eng |
dc.subject.other | Hydride elimination | eng |
dc.subject.other | Rate determining step | eng |
dc.subject.other | Ruthenium complexes | eng |
dc.subject.other | Ruthenium compounds | eng |
dc.title | Efficient methylation of anilines with methanol catalysed by cyclometalated ruthenium complexes | eng |
dc.type | Article | eng |
dc.type | Text | eng |
tib.accessRights | openAccess | eng |
wgl.contributor | LIKAT | eng |
wgl.subject | Chemie | eng |
wgl.type | Zeitschriftenartikel | eng |
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