Efficient methylation of anilines with methanol catalysed by cyclometalated ruthenium complexes

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dc.bibliographicCitation.firstPage2512eng
dc.bibliographicCitation.issue7eng
dc.bibliographicCitation.lastPage2517eng
dc.bibliographicCitation.volume11eng
dc.contributor.authorPiehl, Patrick
dc.contributor.authorAmuso, Roberta
dc.contributor.authorSpannenberg, Anke
dc.contributor.authorGabriele, Bartolo
dc.contributor.authorNeumann, Helfried
dc.contributor.authorBeller, Matthias
dc.date.accessioned2022-03-25T07:24:45Z
dc.date.available2022-03-25T07:24:45Z
dc.date.issued2021
dc.description.abstractCyclometalated ruthenium complexes4-10allow the effective methylation of anilines with methanol to selectively giveN-methylanilines. This hydrogen autotransfer procedure proceeds under mild conditions (60 °C) in a practical manner (NaOH as base). Mechanistic investigations suggest an active homogenous ruthenium complex and β-hydride elimination of methanol as the rate determining step. © The Royal Society of Chemistry 2021.eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/8376
dc.identifier.urihttps://doi.org/10.34657/7414
dc.language.isoengeng
dc.publisherLondon : RSC Publ.eng
dc.relation.doihttps://doi.org/10.1039/d0cy02210a
dc.relation.essn2044-4761
dc.relation.ispartofseriesCatalysis Science and Technology 11 (2021), Nr. 7eng
dc.relation.issn2044-4753
dc.rights.licenseCC BY-NC 3.0 Unportedeng
dc.rights.urihttps://creativecommons.org/licenses/by-nc/3.0/eng
dc.subjectAlkylationeng
dc.subjectAnilineeng
dc.subjectMethanoleng
dc.subjectMethylationeng
dc.subjectSodium hydroxideeng
dc.subjectAuto-transfereng
dc.subjectHydride eliminationeng
dc.subjectRate determining stepeng
dc.subjectRuthenium complexeseng
dc.subjectRuthenium compoundseng
dc.subject.ddc540eng
dc.titleEfficient methylation of anilines with methanol catalysed by cyclometalated ruthenium complexeseng
dc.typearticleeng
dc.typeTexteng
dcterms.bibliographicCitation.journalTitleCatalysis Science & Technologyeng
tib.accessRightsopenAccesseng
wgl.contributorLIKATeng
wgl.subjectChemieeng
wgl.typeZeitschriftenartikeleng
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