Synthetic strategies to bicyclic tetraphosphanes using P1, P2 and P4 building blocks
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Date
2015
Volume
45
Issue
5
Journal
Dalton transactions : a journal of inorganic chemistry, including bioinorganic, organometallic, and solid-state chemistry
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Publisher
London : Soc.
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Abstract
Different reactions of Mes* substituted phosphanes (Mes* = 2,4,6-tri-tert-butylphenyl) led to the formation of the bicyclic tetraphosphane MesP4Mes (5) and its unknown Lewis acid adduct 5·GaCl3. In this context, the endo–exo isomer of 5 was fully characterized for the first time. The synthesis was achieved by reactions involving “self-assembly” of the P4 scaffold from P1 building blocks (i.e. primary phosphanes) or by reactions starting from P2 or P4 scaffolds (i.e. a diphosphene or cyclic tetraphosphane). Furthermore, interconversion between the exo–exo and endo–exo isomer were studied by 31P NMR spectroscopy. All compounds were fully characterized by experimental as well as computational methods.
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CC BY 3.0 Unported