Tailored Palladium Catalysts for Selective Synthesis of Conjugated Enynes by Monocarbonylation of 1,3-Diynes
dc.bibliographicCitation.firstPage | 9032 | eng |
dc.bibliographicCitation.issue | 23 | eng |
dc.bibliographicCitation.journalTitle | Angewandte Chemie : a journal of the Gesellschaft Deutscher Chemiker : International edition | eng |
dc.bibliographicCitation.lastPage | 9040 | eng |
dc.bibliographicCitation.volume | 59 | eng |
dc.contributor.author | Liu, Jiawang | |
dc.contributor.author | Yang, Ji | |
dc.contributor.author | Schneider, Carolin | |
dc.contributor.author | Franke, Robert | |
dc.contributor.author | Jackstell, Ralf | |
dc.contributor.author | Beller, Matthias | |
dc.date.accessioned | 2021-09-03T05:08:01Z | |
dc.date.available | 2021-09-03T05:08:01Z | |
dc.date.issued | 2020 | |
dc.description.abstract | For the first time, the monoalkoxycarbonylation of easily available 1,3-diynes to give synthetically useful conjugated enynes has been realized. Key to success was the design and utilization of the new ligand 2,2′-bis(tert-butyl(pyridin-2-yl)phosphanyl)-1,1′-binaphthalene (Neolephos), which permits the palladium-catalyzed selective carbonylation under mild conditions, providing a general preparation of functionalized 1,3-enynes in good-to-high yields with excellent chemoselectivities. Synthetic applications that showcase the possibilities of this novel methodology include an efficient one-pot synthesis of 4-aryl-4H-pyrans as well as the rapid construction of various heterocyclic, bicyclic, and polycyclic compounds. © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. | eng |
dc.description.version | publishedVersion | eng |
dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/6680 | |
dc.identifier.uri | https://doi.org/10.34657/5727 | |
dc.language.iso | eng | eng |
dc.publisher | Weinheim : Wiley-VCH | eng |
dc.relation.doi | https://doi.org/10.1002/anie.201915386 | |
dc.relation.essn | 1521-3773 | |
dc.relation.issn | 0570-0833 | |
dc.relation.issn | 1433-7851 | |
dc.rights.license | CC BY-NC 4.0 Unported | eng |
dc.rights.uri | https://creativecommons.org/licenses/by-nc/4.0/ | eng |
dc.subject.ddc | 540 | eng |
dc.subject.other | conjugated enynes | eng |
dc.subject.other | monocarbonylation | eng |
dc.subject.other | P ligands | eng |
dc.subject.other | palladium | eng |
dc.subject.other | selectivity | eng |
dc.title | Tailored Palladium Catalysts for Selective Synthesis of Conjugated Enynes by Monocarbonylation of 1,3-Diynes | eng |
dc.type | Article | eng |
dc.type | Text | eng |
tib.accessRights | openAccess | eng |
wgl.contributor | LIKAT | eng |
wgl.subject | Chemie | eng |
wgl.type | Zeitschriftenartikel | eng |
Files
Original bundle
1 - 1 of 1
Loading...
- Name:
- Tailored Palladium Catalysts for Selective Synthesis of Conjugated Enynes by Monocarbonylation of 1,3-Diynes.pdf
- Size:
- 5.55 MB
- Format:
- Adobe Portable Document Format
- Description: