Synthesis of Molybdenum Pincer Complexes and Their Application in the Catalytic Hydrogenation of Nitriles

dc.bibliographicCitation.firstPage4543eng
dc.bibliographicCitation.issue18eng
dc.bibliographicCitation.journalTitleChemCatChemeng
dc.bibliographicCitation.lastPage4549eng
dc.bibliographicCitation.volume12eng
dc.contributor.authorLeischner, Thomas
dc.contributor.authorSpannenberg, Anke
dc.contributor.authorJunge, Kathrin
dc.contributor.authorBeller, Matthias
dc.date.accessioned2021-09-06T07:12:38Z
dc.date.available2021-09-06T07:12:38Z
dc.date.issued2020
dc.description.abstractA series of molybdenum(0), (I) and (II) complexes ligated by different PNP and NNN pincer ligands were synthesized and structurally characterized. Along with previously described Mo−PNP complexes Mo-1 and Mo-2, all prepared compounds were tested in the catalytic hydrogenation of aromatic nitriles to primary amines. Among the applied catalysts, Mo-1 is particularly well suited for the hydrogenation of electron-rich benzonitriles. Additionally, two aliphatic nitriles were transformed into the desired products in 80 and 86 %, respectively. Moreover, catalytic intermediate Mo-1a was isolated and its role in the catalytic cycle was subsequently demonstrated. © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/6705
dc.identifier.urihttps://doi.org/10.34657/5752
dc.language.isoengeng
dc.publisherWeinheim : Wiley-VCH Verlageng
dc.relation.doihttps://doi.org/10.1002/cctc.202000736
dc.relation.essn1867-3899
dc.relation.issn1867-3880
dc.rights.licenseCC BY-NC 4.0 Unportedeng
dc.rights.urihttps://creativecommons.org/licenses/by-nc/4.0/eng
dc.subject.ddc540eng
dc.subject.otherhydrogenationeng
dc.subject.othermolybdenumeng
dc.subject.othernitrileeng
dc.subject.otherpincer complexeseng
dc.subject.otherprimary amineeng
dc.titleSynthesis of Molybdenum Pincer Complexes and Their Application in the Catalytic Hydrogenation of Nitrileseng
dc.typeArticleeng
dc.typeTexteng
tib.accessRightsopenAccesseng
wgl.contributorLIKATeng
wgl.subjectChemieeng
wgl.typeZeitschriftenartikeleng
Files
Original bundle
Now showing 1 - 1 of 1
Loading...
Thumbnail Image
Name:
Synthesis of Molybdenum Pincer Complexes and Their Application in the Catalytic Hydrogenation of Nitriles.pdf
Size:
2.42 MB
Format:
Adobe Portable Document Format
Description:
Collections