Synthesis of Molybdenum Pincer Complexes and Their Application in the Catalytic Hydrogenation of Nitriles
dc.bibliographicCitation.firstPage | 4543 | eng |
dc.bibliographicCitation.issue | 18 | eng |
dc.bibliographicCitation.journalTitle | ChemCatChem | eng |
dc.bibliographicCitation.lastPage | 4549 | eng |
dc.bibliographicCitation.volume | 12 | eng |
dc.contributor.author | Leischner, Thomas | |
dc.contributor.author | Spannenberg, Anke | |
dc.contributor.author | Junge, Kathrin | |
dc.contributor.author | Beller, Matthias | |
dc.date.accessioned | 2021-09-06T07:12:38Z | |
dc.date.available | 2021-09-06T07:12:38Z | |
dc.date.issued | 2020 | |
dc.description.abstract | A series of molybdenum(0), (I) and (II) complexes ligated by different PNP and NNN pincer ligands were synthesized and structurally characterized. Along with previously described Mo−PNP complexes Mo-1 and Mo-2, all prepared compounds were tested in the catalytic hydrogenation of aromatic nitriles to primary amines. Among the applied catalysts, Mo-1 is particularly well suited for the hydrogenation of electron-rich benzonitriles. Additionally, two aliphatic nitriles were transformed into the desired products in 80 and 86 %, respectively. Moreover, catalytic intermediate Mo-1a was isolated and its role in the catalytic cycle was subsequently demonstrated. © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. | eng |
dc.description.version | publishedVersion | eng |
dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/6705 | |
dc.identifier.uri | https://doi.org/10.34657/5752 | |
dc.language.iso | eng | eng |
dc.publisher | Weinheim : Wiley-VCH Verlag | eng |
dc.relation.doi | https://doi.org/10.1002/cctc.202000736 | |
dc.relation.essn | 1867-3899 | |
dc.relation.issn | 1867-3880 | |
dc.rights.license | CC BY-NC 4.0 Unported | eng |
dc.rights.uri | https://creativecommons.org/licenses/by-nc/4.0/ | eng |
dc.subject.ddc | 540 | eng |
dc.subject.other | hydrogenation | eng |
dc.subject.other | molybdenum | eng |
dc.subject.other | nitrile | eng |
dc.subject.other | pincer complexes | eng |
dc.subject.other | primary amine | eng |
dc.title | Synthesis of Molybdenum Pincer Complexes and Their Application in the Catalytic Hydrogenation of Nitriles | eng |
dc.type | Article | eng |
dc.type | Text | eng |
tib.accessRights | openAccess | eng |
wgl.contributor | LIKAT | eng |
wgl.subject | Chemie | eng |
wgl.type | Zeitschriftenartikel | eng |
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