Few-cycle laser driven reaction nanoscopy on aerosolized silica nanoparticles
dc.bibliographicCitation.firstPage | 4655 | eng |
dc.bibliographicCitation.journalTitle | Nature Communications | eng |
dc.bibliographicCitation.volume | 10 | eng |
dc.contributor.author | Rupp, Philipp | |
dc.contributor.author | Burger, Christian | |
dc.contributor.author | Kling, Nora G | |
dc.contributor.author | Kübel, Matthias | |
dc.contributor.author | Mitra, Sambit | |
dc.contributor.author | Rosenberger, Philipp | |
dc.contributor.author | Weatherby, Thomas | |
dc.contributor.author | Saito, Nariyuki | |
dc.contributor.author | Itatani, Jiro | |
dc.contributor.author | Alnaser, Ali S. | |
dc.contributor.author | Raschke, Markus B. | |
dc.contributor.author | Rühl, Eckart | |
dc.contributor.author | Schlander, Annika | |
dc.contributor.author | Gallei, Markus | |
dc.contributor.author | Seiffert, Lennart | |
dc.contributor.author | Fennel, Thomas | |
dc.contributor.author | Bergues, Boris | |
dc.contributor.author | Kling, Matthias F. | |
dc.date.accessioned | 2022-11-18T08:45:55Z | |
dc.date.available | 2022-11-18T08:45:55Z | |
dc.date.issued | 2019 | |
dc.description.abstract | Nanoparticles offer unique properties as photocatalysts with large surface areas. Under irradiation with light, the associated near-fields can induce, enhance, and control molecular adsorbate reactions on the nanoscale. So far, however, there is no simple method available to spatially resolve the near-field induced reaction yield on the surface of nanoparticles. Here we close this gap by introducing reaction nanoscopy based on three-dimensional momentum-resolved photoionization. The technique is demonstrated for the spatially selective proton generation in few-cycle laser-induced dissociative ionization of ethanol and water on SiO2 nanoparticles, resolving a pronounced variation across the particle surface. The results are modeled and reproduced qualitatively by electrostatic and quasi-classical mean-field Mie Monte-Carlo (M3C) calculations. Reaction nanoscopy is suited for a wide range of isolated nanosystems and can provide spatially resolved ultrafast reaction dynamics on nanoparticles, clusters, and droplets. | eng |
dc.description.version | publishedVersion | eng |
dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/10368 | |
dc.identifier.uri | http://dx.doi.org/10.34657/9404 | |
dc.language.iso | eng | eng |
dc.publisher | [London] : Nature Publishing Group UK | eng |
dc.relation.doi | https://doi.org/10.1038/s41467-019-12580-0 | |
dc.relation.essn | 2041-1723 | |
dc.rights.license | CC BY 4.0 Unported | eng |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | eng |
dc.subject.ddc | 500 | eng |
dc.subject.other | analytic method | eng |
dc.subject.other | dissociation | eng |
dc.subject.other | ionization | eng |
dc.subject.other | laser driven reaction nanoscopy | eng |
dc.subject.other | Monte Carlo method | eng |
dc.subject.other | nanotechnology | eng |
dc.subject.other | photochemistry | eng |
dc.subject.other | qualitative analysis | eng |
dc.subject.other | static electricity | eng |
dc.subject.other | surface property | eng |
dc.subject.other | alcohol | eng |
dc.subject.other | proton | eng |
dc.subject.other | silica nanoparticle | eng |
dc.subject.other | water | eng |
dc.title | Few-cycle laser driven reaction nanoscopy on aerosolized silica nanoparticles | eng |
dc.type | Article | eng |
dc.type | Text | eng |
tib.accessRights | openAccess | eng |
wgl.contributor | MBI | eng |
wgl.subject | Physik | eng |
wgl.type | Zeitschriftenartikel | eng |
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