Ambient Hydrogenation and Deuteration of Alkenes Using a Nanostructured Ni-Core-Shell Catalyst
dc.bibliographicCitation.firstPage | 18591 | eng |
dc.bibliographicCitation.issue | 34 | eng |
dc.bibliographicCitation.journalTitle | Angewandte Chemie - International Edition | eng |
dc.bibliographicCitation.lastPage | 18598 | eng |
dc.bibliographicCitation.volume | 60 | eng |
dc.contributor.author | Gao, Jie | |
dc.contributor.author | Ma, Rui | |
dc.contributor.author | Feng, Lu | |
dc.contributor.author | Liu, Yuefeng | |
dc.contributor.author | Jackstell, Ralf | |
dc.contributor.author | Jagadeesh, Rajenahally V. | |
dc.contributor.author | Beller, Matthias | |
dc.date.accessioned | 2022-01-31T14:04:25Z | |
dc.date.available | 2022-01-31T14:04:25Z | |
dc.date.issued | 2021 | |
dc.description.abstract | A general protocol for the selective hydrogenation and deuteration of a variety of alkenes is presented. Key to success for these reactions is the use of a specific nickel-graphitic shell-based core–shell-structured catalyst, which is conveniently prepared by impregnation and subsequent calcination of nickel nitrate on carbon at 450 °C under argon. Applying this nanostructured catalyst, both terminal and internal alkenes, which are of industrial and commercial importance, were selectively hydrogenated and deuterated at ambient conditions (room temperature, using 1 bar hydrogen or 1 bar deuterium), giving access to the corresponding alkanes and deuterium-labeled alkanes in good to excellent yields. The synthetic utility and practicability of this Ni-based hydrogenation protocol is demonstrated by gram-scale reactions as well as efficient catalyst recycling experiments. © 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH | eng |
dc.description.version | publishedVersion | eng |
dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/7967 | |
dc.identifier.uri | https://doi.org/10.34657/7008 | |
dc.language.iso | eng | eng |
dc.publisher | Weinheim : Wiley-VCH | eng |
dc.relation.doi | https://doi.org/10.1002/anie.202105492 | |
dc.relation.essn | 1521-3773 | |
dc.rights.license | CC BY-NC 4.0 Unported | eng |
dc.rights.uri | https://creativecommons.org/licenses/by-nc/4.0/ | eng |
dc.subject.ddc | 540 | eng |
dc.subject.other | alkenes | eng |
dc.subject.other | catalysis | eng |
dc.subject.other | deuteration | eng |
dc.subject.other | hydrogenation | eng |
dc.subject.other | nanoparticles | eng |
dc.title | Ambient Hydrogenation and Deuteration of Alkenes Using a Nanostructured Ni-Core-Shell Catalyst | eng |
dc.type | Article | eng |
dc.type | Text | eng |
tib.accessRights | openAccess | eng |
wgl.contributor | LIKAT | eng |
wgl.subject | Chemie | eng |
wgl.type | Zeitschriftenartikel | eng |
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