Single molecule level plasmonic catalysis – a dilution study of p-nitrothiophenol on gold dimers

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Date
2015
Volume
51
Issue
15
Journal
Series Titel
Book Title
Publisher
Cambridge : Soc.
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Abstract

Surface plasmons on isolated gold dimers can initiate intermolecular reactions of adsorbed p-nitrothiophenol. At the single molecule level when dimerization is not possible an intramolecular reaction can be observed. Experimental evidence indicates that plasmon-induced hot electrons provide the required activation energy.

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Keywords
4 nitrothiophenol, dimer, gold nanoparticle, thiophenol derivative, unclassified drug, catalysis, dimerization, electron, scanning electron microscopy
Citation
Zhang, Z., Deckert-Gaudig, T., Singh, P., & Deckert, V. (2015). Single molecule level plasmonic catalysis – a dilution study of p-nitrothiophenol on gold dimers. 51(15). https://doi.org//10.1039/c4cc09008j
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CC BY 3.0 Unported