A thiazolo[5,4-: D] thiazole-bridged porphyrin organic framework as a promising nonlinear optical material
dc.bibliographicCitation.firstPage | 11025 | eng |
dc.bibliographicCitation.issue | 74 | eng |
dc.bibliographicCitation.journalTitle | Chemical Communications | eng |
dc.bibliographicCitation.lastPage | 11028 | eng |
dc.bibliographicCitation.volume | 55 | eng |
dc.contributor.author | Samal, Mahalaxmi | |
dc.contributor.author | Valligatla, Sreeramulu | |
dc.contributor.author | Saad, Nabil A. | |
dc.contributor.author | Rao, M. Veeramohan | |
dc.contributor.author | Rao, D. Narayana | |
dc.contributor.author | Sahu, Rojalin | |
dc.contributor.author | Biswal, Bishnu P. | |
dc.date.accessioned | 2021-08-20T08:51:21Z | |
dc.date.available | 2021-08-20T08:51:21Z | |
dc.date.issued | 2019 | |
dc.description.abstract | Porphyrin-based porous organic frameworks are an important group of materials gaining interest due to their structural diversity and distinct opto-electronic properties. However, these materials are seldom explored for nonlinear optical (NLO) applications. In this work, we investigate a thiazolo[5,4-d]thiazole-bridged porous, porphyrin framework (Por-TzTz-POF) with promising NLO properties. The planar TzTz moiety coupled with integrated porphyrin units enables efficient π-conjugation and charge distribution in the Por-TzTz-POF resulting in a high nonlinear absorption coefficient (β = 1100 cm GW-1) with figure of merit (FoM) σ1/σ0 = 5571, in contrast to analogous molecules and material counterparts e.g. metal-organic frameworks (MOFs; β = ∼0.3-0.5 cm GW-1), molecular porphyrins (β = ∼100-400 cm GW-1), graphene (β = 900 cm GW-1), and covalent organic frameworks (Por-COF-HH; β = 1040 cm GW-1 and FoM = 3534). This journal is © The Royal Society of Chemistry. | eng |
dc.description.version | publishedVersion | eng |
dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/6555 | |
dc.identifier.uri | https://doi.org/10.34657/5602 | |
dc.language.iso | eng | eng |
dc.publisher | London : Royal Society of Chemistry (RSC) | eng |
dc.relation.doi | https://doi.org/10.1039/c9cc05415d | |
dc.relation.essn | 1364-548X | |
dc.relation.issn | 0009-241X | |
dc.relation.issn | 0022-4936 | |
dc.relation.issn | 1359-7345 | |
dc.rights.license | CC BY 3.0 Unported | eng |
dc.rights.uri | https://creativecommons.org/licenses/by/3.0/ | eng |
dc.subject.ddc | 540 | eng |
dc.subject.other | graphene | eng |
dc.subject.other | metal organic framework | eng |
dc.subject.other | porphyrin derivative | eng |
dc.subject.other | thiazole derivative | eng |
dc.subject.other | absorption | eng |
dc.subject.other | chemical analysis | eng |
dc.subject.other | chemical bond | eng |
dc.subject.other | chemical interaction | eng |
dc.subject.other | chemical structure | eng |
dc.subject.other | decomposition | eng |
dc.subject.other | density functional theory | eng |
dc.subject.other | electron transport | eng |
dc.subject.other | fluorescence | eng |
dc.subject.other | nuclear magnetic resonance spectroscopy | eng |
dc.subject.other | porosity | eng |
dc.subject.other | scanning electron microscopy | eng |
dc.subject.other | structure activity relation | eng |
dc.subject.other | thermogravimetry | eng |
dc.subject.other | thermostability | eng |
dc.subject.other | transmission electron microscopy | eng |
dc.subject.other | X ray diffraction | eng |
dc.title | A thiazolo[5,4-: D] thiazole-bridged porphyrin organic framework as a promising nonlinear optical material | eng |
dc.type | Article | eng |
dc.type | Text | eng |
tib.accessRights | openAccess | eng |
wgl.contributor | IFWD | eng |
wgl.subject | Chemie | eng |
wgl.type | Zeitschriftenartikel | eng |
Files
Original bundle
1 - 1 of 1
Loading...
- Name:
- c9cc05415d-1.pdf
- Size:
- 2.42 MB
- Format:
- Adobe Portable Document Format
- Description: