Manganese-catalyzed selective C–H activation and deuteration by means of a catalytic transient directing group strategy
dc.bibliographicCitation.firstPage | 1137 | eng |
dc.bibliographicCitation.issue | 9 | eng |
dc.bibliographicCitation.journalTitle | Chemical Communications | eng |
dc.bibliographicCitation.lastPage | 1140 | eng |
dc.bibliographicCitation.volume | 57 | eng |
dc.contributor.author | Kopf, Sara | |
dc.contributor.author | Neumann, Helfried | |
dc.contributor.author | Beller, Matthias | |
dc.date.accessioned | 2022-03-29T09:36:58Z | |
dc.date.available | 2022-03-29T09:36:58Z | |
dc.date.issued | 2021 | |
dc.description.abstract | A novel manganese-catalyzed C-H activation methodology for selective hydrogen isotope exchange of benzaldehydes is presented. Using D2O as a cheap and convenient source of deuterium, the reaction proceeds with excellent functional group tolerance. Highortho-selectivity is achieved in the presence of catalytic amounts of specific amines, whichin situform a transient directing group. © The Royal Society of Chemistry 2021. | eng |
dc.description.version | publishedVersion | eng |
dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/8433 | |
dc.identifier.uri | https://doi.org/10.34657/7471 | |
dc.language.iso | eng | eng |
dc.publisher | London : Royal Society of Chemistry (RSC) | eng |
dc.relation.doi | https://doi.org/10.1039/d0cc07675a | |
dc.relation.essn | 1364-548X | |
dc.rights.license | CC BY-NC 3.0 Unported | eng |
dc.rights.uri | https://creativecommons.org/licenses/by-nc/3.0/ | eng |
dc.subject.ddc | 540 | eng |
dc.subject.other | Activation analysis | eng |
dc.subject.other | Amines | eng |
dc.subject.other | Catalysis | eng |
dc.subject.other | Chemical activation | eng |
dc.subject.other | Manganese | eng |
dc.subject.other | C-h activation | eng |
dc.subject.other | Catalytic amounts | eng |
dc.subject.other | Deuterations | eng |
dc.subject.other | Directing groups | eng |
dc.subject.other | Hydrogen isotope exchange | eng |
dc.subject.other | benzaldehyde derivative | eng |
dc.subject.other | carbon | eng |
dc.subject.other | deuterium | eng |
dc.subject.other | functional group | eng |
dc.subject.other | hydrogen | eng |
dc.subject.other | chemical bond | eng |
dc.subject.other | chemical phenomena | eng |
dc.subject.other | ortho selectivity | eng |
dc.title | Manganese-catalyzed selective C–H activation and deuteration by means of a catalytic transient directing group strategy | eng |
dc.type | Article | eng |
dc.type | Text | eng |
tib.accessRights | openAccess | eng |
wgl.contributor | LIKAT | eng |
wgl.subject | Chemie | eng |
wgl.type | Zeitschriftenartikel | eng |
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