Manganese-catalyzed selective C–H activation and deuteration by means of a catalytic transient directing group strategy

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dc.bibliographicCitation.firstPage1137eng
dc.bibliographicCitation.issue9eng
dc.bibliographicCitation.lastPage1140eng
dc.bibliographicCitation.volume57eng
dc.contributor.authorKopf, Sara
dc.contributor.authorNeumann, Helfried
dc.contributor.authorBeller, Matthias
dc.date.accessioned2022-03-29T09:36:58Z
dc.date.available2022-03-29T09:36:58Z
dc.date.issued2021
dc.description.abstractA novel manganese-catalyzed C-H activation methodology for selective hydrogen isotope exchange of benzaldehydes is presented. Using D2O as a cheap and convenient source of deuterium, the reaction proceeds with excellent functional group tolerance. Highortho-selectivity is achieved in the presence of catalytic amounts of specific amines, whichin situform a transient directing group. © The Royal Society of Chemistry 2021.eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/8433
dc.identifier.urihttps://doi.org/10.34657/7471
dc.language.isoengeng
dc.publisherLondon : Royal Society of Chemistry (RSC)eng
dc.relation.doihttps://doi.org/10.1039/d0cc07675a
dc.relation.essn1364-548X
dc.relation.ispartofseriesChemical Communications 57 (2021), Nr. 9eng
dc.rights.licenseCC BY-NC 3.0 Unportedeng
dc.rights.urihttps://creativecommons.org/licenses/by-nc/3.0/eng
dc.subjectActivation analysiseng
dc.subjectAmineseng
dc.subjectCatalysiseng
dc.subjectChemical activationeng
dc.subjectManganeseeng
dc.subjectC-h activationeng
dc.subjectCatalytic amountseng
dc.subjectDeuterationseng
dc.subjectDirecting groupseng
dc.subjectHydrogen isotope exchangeeng
dc.subjectbenzaldehyde derivativeeng
dc.subjectcarboneng
dc.subjectdeuteriumeng
dc.subjectfunctional groupeng
dc.subjecthydrogeneng
dc.subjectchemical bondeng
dc.subjectchemical phenomenaeng
dc.subjectortho selectivityeng
dc.subject.ddc540eng
dc.titleManganese-catalyzed selective C–H activation and deuteration by means of a catalytic transient directing group strategyeng
dc.typearticleeng
dc.typeTexteng
dcterms.bibliographicCitation.journalTitleChemical Communicationseng
tib.accessRightsopenAccesseng
wgl.contributorLIKATeng
wgl.subjectChemieeng
wgl.typeZeitschriftenartikeleng
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