Cobalt Single-Atom Catalysts with High Stability for Selective Dehydrogenation of Formic Acid
dc.bibliographicCitation.firstPage | 15849 | eng |
dc.bibliographicCitation.issue | 37 | eng |
dc.bibliographicCitation.lastPage | 15854 | eng |
dc.bibliographicCitation.volume | 59 | eng |
dc.contributor.author | Li, Xiang | |
dc.contributor.author | Surkus, Annette-Enrica | |
dc.contributor.author | Rabeah, Jabor | |
dc.contributor.author | Anwar, Muhammad | |
dc.contributor.author | Dastigir, Sarim | |
dc.contributor.author | Junge, Henrik | |
dc.contributor.author | Brückner, Angelika | |
dc.contributor.author | Beller, Matthias | |
dc.date.accessioned | 2021-09-03T04:59:48Z | |
dc.date.available | 2021-09-03T04:59:48Z | |
dc.date.issued | 2020 | |
dc.description.abstract | Metal–organic framework (MOF)-derived Co-N-C catalysts with isolated single cobalt atoms have been synthesized and compared with cobalt nanoparticles for formic acid dehydrogenation. The atomically dispersed Co-N-C catalyst achieves superior activity, better acid resistance, and improved long-term stability compared with nanoparticles synthesized by a similar route. High-angle annular dark-field–scanning transmission electron microscopy, X-ray photoelectron spectroscopy, electron paramagnetic resonance, and X-ray absorption fine structure characterizations reveal the formation of CoIINx centers as active sites. The optimal low-cost catalyst is a promising candidate for liquid H2 generation. © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. | eng |
dc.description.version | publishedVersion | eng |
dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/6679 | |
dc.identifier.uri | https://doi.org/10.34657/5726 | |
dc.language.iso | eng | eng |
dc.publisher | Weinheim : Wiley-VCH | eng |
dc.relation.doi | https://doi.org/10.1002/anie.202004125 | |
dc.relation.essn | 1521-3773 | |
dc.relation.ispartofseries | Angewandte Chemie : a journal of the Gesellschaft Deutscher Chemiker : International edition 59 (2020), Nr. 37 | eng |
dc.relation.issn | 0570-0833 | |
dc.relation.issn | 1433-7851 | |
dc.rights.license | CC BY-NC 4.0 Unported | eng |
dc.rights.uri | https://creativecommons.org/licenses/by-nc/4.0/ | eng |
dc.subject | cobalt | eng |
dc.subject | dehydrogenation | eng |
dc.subject | energy | eng |
dc.subject | nanoparticles | eng |
dc.subject | single-atom catalysts | eng |
dc.subject.ddc | 540 | eng |
dc.title | Cobalt Single-Atom Catalysts with High Stability for Selective Dehydrogenation of Formic Acid | eng |
dc.type | article | eng |
dc.type | Text | eng |
dcterms.bibliographicCitation.journalTitle | Angewandte Chemie : a journal of the Gesellschaft Deutscher Chemiker : International edition | eng |
tib.accessRights | openAccess | eng |
wgl.contributor | LIKAT | eng |
wgl.subject | Chemie | eng |
wgl.type | Zeitschriftenartikel | eng |
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