(+)-{1,2-Bis[(2R,5R)-2,5-dimethyl-phospho-lan-1-yl]ethane- κ2 P,P′}(η4-cyclo-octa-1,5-diene) rhodium(I) tetra-fluorido-borate

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dc.bibliographicCitation.firstPagem721eng
dc.bibliographicCitation.issue6eng
dc.bibliographicCitation.lastPage22eng
dc.bibliographicCitation.volume66eng
dc.contributor.authorSchulz, S.
dc.contributor.authorDrexler, H.-J.
dc.contributor.authorHeller, D.
dc.date.accessioned2020-08-11T08:32:48Z
dc.date.available2020-08-11T08:32:48Z
dc.date.issued2010
dc.description.abstractThe title compound, [Rh(C8H12)(C14H 28P2)]BF4, exhibits a rhodium(I) complex cation with a bidentate bis-phosphine ligand and a bidentate η2, η2-coordinated cyclo-octa-1,5-diene. Together the ligands create a slightly distorted square-planar cordination environment for the Rh(I) atom. There are three mol-ecules in the asymmetric unit and intra-molecular P - Rh - P bite angles of 82.78 (5), 82.97 (6) and 83.09 (5)° are observed. The dihedral angles between the P - Rh - P and the X - Rh - X planes (X is the centroid of a double bond) are 14.7 (1), 14.8 (1) and 15.3 (1)°. The structure exhibits disorder of one cyclo-octa-diene ligand as well as one BF4 anion.eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://doi.org/10.34657/4045
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/5416
dc.language.isoengeng
dc.publisherChester : International Union of Crystallographyeng
dc.relation.doihttps://doi.org/10.1107/S1600536810019859
dc.relation.ispartofseriesActa Crystallographica Section E: Structure Reports Online 66 (2010), 6eng
dc.relation.issn1600-5368
dc.rights.licenseCC BY 4.0 Unportedeng
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/eng
dc.subjectCrystal structureeng
dc.subjectChemistryeng
dc.subjectCrystallographyeng
dc.subject.ddc540eng
dc.title(+)-{1,2-Bis[(2R,5R)-2,5-dimethyl-phospho-lan-1-yl]ethane- κ2 P,P′}(η4-cyclo-octa-1,5-diene) rhodium(I) tetra-fluorido-borateeng
dc.typearticleeng
dc.typeTexteng
dcterms.bibliographicCitation.journalTitleActa Crystallographica Section E: Structure Reports Onlineeng
tib.accessRightsopenAccesseng
wgl.contributorLIKATeng
wgl.subjectChemieeng
wgl.typeZeitschriftenartikeleng
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