Rhodium-catalyzed borylative carbon monoxide reduction to gem-diborylmethane

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1-s2.0-S1566736720302818-main.pdf(483.67 KB)
Date
2021
Authors
Volume
149
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Journal
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Book Title
Publisher
Amsterdam [u.a.] : Elsevier
Link to publishers version
https://doi.org/10.1016/j.catcom.2020.106205
Abstract

Herein, we developed a rhodium-catalyzed reduction of CO with bis(pinacolato)diboron (B2pin2) under atmospheric pressure of CO with silane as the hydride source, gem-diborylmethane [H2C(Bpin)2] as a versatile and fundamental C1 compound can be formed. Notably, this is the first example on transition metal-catalyzed borylation of CO. © 2020 The Author(s)

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Keywords
Borylation, Carbon monoxide, Gem-Diborylmethane, Reduction, Rhodium catalyst
URI
https://oa.tib.eu/renate/handle/123456789/8344
 https://doi.org/10.34657/7382
Citation
Xua, J.-X., Wu, F.-P., & Wu, X.-F. (2021). Rhodium-catalyzed borylative carbon monoxide reduction to gem-diborylmethane. 149. https://doi.org//10.1016/j.catcom.2020.106205
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Chemie
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CC BY-NC-ND 4.0 Unported
https://creativecommons.org/licenses/by-nc-nd/4.0/