Rhodium-catalyzed borylative carbon monoxide reduction to gem-diborylmethane
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Date
2021
Authors
Volume
149
Issue
Journal
Catalysis Communications
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Publisher
Amsterdam [u.a.] : Elsevier
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Abstract
Herein, we developed a rhodium-catalyzed reduction of CO with bis(pinacolato)diboron (B2pin2) under atmospheric pressure of CO with silane as the hydride source, gem-diborylmethane [H2C(Bpin)2] as a versatile and fundamental C1 compound can be formed. Notably, this is the first example on transition metal-catalyzed borylation of CO. © 2020 The Author(s)
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Xua, J.-X., Wu, F.-P., & Wu, X.-F. (2021). Rhodium-catalyzed borylative carbon monoxide reduction to gem-diborylmethane (Amsterdam [u.a.] : Elsevier). Amsterdam [u.a.] : Elsevier. https://doi.org//10.1016/j.catcom.2020.106205
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CC BY-NC-ND 4.0 Unported