Intermolecular hydrogen bonding in isostructural pincer complexes [OH-(t-BuPOCOPt-Bu)MCl] (M = Pd and Pt)

dc.bibliographicCitation.firstPage1011eng
dc.bibliographicCitation.volume75eng
dc.contributor.authorJoksch, M.
dc.contributor.authorSpannenberg, A.
dc.contributor.authorBeweries, T.
dc.date.accessioned2020-07-13T11:01:17Z
dc.date.available2020-07-13T11:01:17Z
dc.date.issued2019
dc.description.abstractIn the crystal structure of the isostructural title compounds, namely {2,6-bis[(di-tert-butylphosphanyl)oxy]-4-hydroxyphenyl}chloridopalladium(II), [Pd(C22H39O3P2)Cl], 1, and {2,6-bis[(di-tert-butylphosphanyl)oxy]-4-hydroxyphenyl}chloridoplatinum(II), [Pt(C22H39O3P2)Cl], 2, the metal centres are coordinated in a distorted square-planar fashion by the POCOP pincer fragment and the chloride ligand. Both complexes form strong hydrogen-bonded chain structures through an interaction of the OH group in the 4-position of the aromatic POCOP backbone with the halide ligand.eng
dc.description.sponsorshipLeibniz_Fondseng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://doi.org/10.34657/3513
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/4884
dc.language.isoengeng
dc.publisherChester : International Union of Crystallographyeng
dc.relation.doihttps://doi.org/10.1107/S2056989019008491
dc.relation.ispartofseriesActa Crystallographica Section E: Crystallographic Communications 75 (2019)eng
dc.relation.issn2056-9890
dc.rights.licenseCC BY 4.0 Unportedeng
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/eng
dc.subjectCrystal structureeng
dc.subjectHydrogen bondingeng
dc.subjectPalladiumeng
dc.subjectpincer complexeseng
dc.subjectPlatinumeng
dc.subject.ddc540eng
dc.titleIntermolecular hydrogen bonding in isostructural pincer complexes [OH-(t-BuPOCOPt-Bu)MCl] (M = Pd and Pt)eng
dc.typearticleeng
dc.typeTexteng
dcterms.bibliographicCitation.journalTitleActa Crystallographica Section E: Crystallographic Communicationseng
tib.accessRightsopenAccesseng
wgl.contributorLIKATeng
wgl.subjectChemieeng
wgl.typeZeitschriftenartikeleng
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