Intermolecular hydrogen bonding in isostructural pincer complexes [OH-(t-BuPOCOPt-Bu)MCl] (M = Pd and Pt)
dc.bibliographicCitation.firstPage | 1011 | eng |
dc.bibliographicCitation.journalTitle | Acta Crystallographica Section E: Crystallographic Communications | eng |
dc.bibliographicCitation.volume | 75 | eng |
dc.contributor.author | Joksch, M. | |
dc.contributor.author | Spannenberg, A. | |
dc.contributor.author | Beweries, T. | |
dc.date.accessioned | 2020-07-13T11:01:17Z | |
dc.date.available | 2020-07-13T11:01:17Z | |
dc.date.issued | 2019 | |
dc.description.abstract | In the crystal structure of the isostructural title compounds, namely {2,6-bis[(di-tert-butylphosphanyl)oxy]-4-hydroxyphenyl}chloridopalladium(II), [Pd(C22H39O3P2)Cl], 1, and {2,6-bis[(di-tert-butylphosphanyl)oxy]-4-hydroxyphenyl}chloridoplatinum(II), [Pt(C22H39O3P2)Cl], 2, the metal centres are coordinated in a distorted square-planar fashion by the POCOP pincer fragment and the chloride ligand. Both complexes form strong hydrogen-bonded chain structures through an interaction of the OH group in the 4-position of the aromatic POCOP backbone with the halide ligand. | eng |
dc.description.fonds | Leibniz_Fonds | |
dc.description.version | publishedVersion | eng |
dc.identifier.uri | https://doi.org/10.34657/3513 | |
dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/4884 | |
dc.language.iso | eng | eng |
dc.publisher | Chester : International Union of Crystallography | eng |
dc.relation.doi | https://doi.org/10.1107/S2056989019008491 | |
dc.relation.issn | 2056-9890 | |
dc.rights.license | CC BY 4.0 Unported | eng |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | eng |
dc.subject.ddc | 540 | eng |
dc.subject.other | Crystal structure | eng |
dc.subject.other | Hydrogen bonding | eng |
dc.subject.other | Palladium | eng |
dc.subject.other | pincer complexes | eng |
dc.subject.other | Platinum | eng |
dc.title | Intermolecular hydrogen bonding in isostructural pincer complexes [OH-(t-BuPOCOPt-Bu)MCl] (M = Pd and Pt) | eng |
dc.type | Article | eng |
dc.type | Text | eng |
tib.accessRights | openAccess | eng |
wgl.contributor | LIKAT | eng |
wgl.subject | Chemie | eng |
wgl.type | Zeitschriftenartikel | eng |
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