Manganese Catalyzed Asymmetric Transfer Hydrogenation of Ketones Using Chiral Oxamide Ligands

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dc.bibliographicCitation.firstPage503eng
dc.bibliographicCitation.issue4eng
dc.bibliographicCitation.journalTitleSynletteng
dc.bibliographicCitation.lastPage507eng
dc.bibliographicCitation.volume30eng
dc.contributor.authorSchneekönig, Jacob
dc.contributor.authorJunge, Kathrin
dc.contributor.authorBeller, Matthias
dc.date.accessioned2022-10-11T06:53:31Z
dc.date.available2022-10-11T06:53:31Z
dc.date.issued2019
dc.description.abstractThe asymmetric transfer hydrogenation of ketones using isopropyl alcohol (IPA) as hydrogen donor in the presence of novel manganese catalysts is explored. The selective and active systems are easily generated in situ from [MnBr(CO)5] and inexpensive C 2-symmeric bisoxalamide ligands. Under the optimized reaction conditions, the Mn-derived catalyst gave higher enantioselectivity compared with the related ruthenium catalyst.eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/10243
dc.identifier.urihttp://dx.doi.org/10.34657/9279
dc.language.isoengeng
dc.publisherStuttgart [u.a.] : Thiemeeng
dc.relation.doihttps://doi.org/10.1055/s-0037-1611669
dc.relation.essn1437-2096
dc.rights.licenseCC BY-NC-ND 4.0 Unportedeng
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/eng
dc.subject.ddc540eng
dc.subject.otherasymmetriceng
dc.subject.otherchiral ligandseng
dc.subject.otherketoneseng
dc.subject.othermanganeseeng
dc.subject.othertransfer hydrogenationeng
dc.titleManganese Catalyzed Asymmetric Transfer Hydrogenation of Ketones Using Chiral Oxamide Ligandseng
dc.typeArticleeng
dc.typeTexteng
tib.accessRightsopenAccesseng
wgl.contributorLIKATeng
wgl.subjectChemieeng
wgl.typeZeitschriftenartikeleng
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