[N,N-Bis(diphenyl­phosphino)isopropyl­amine]dibromidonickel(II)

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Date

Volume

65

Issue

3

Journal

Acta Crystallographica Section E: Structure Reports Online

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Publisher

Chester : International Union of Crystallography

Abstract

The title compound, [NiBr2(C27H27NP2)], was synthesized by the reaction of NiBr2(dme) (dme is 1,2-dimethoxy-ethane) with N,N-bis-(diphenyl-phosphino)isopropyl-amine in methanol/tetra-hydro-furan. The nickel(II) center is coordinated by two P atoms of the chelating PNP ligand, PH2PN(iPr)PPH2, and two bromide ions in a distorted square-planar geometry.

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CC BY 4.0 Unported