Efficient Synthesis of Novel Plasticizers by Direct Palladium-Catalyzed Di- or Multi-carbonylations
dc.bibliographicCitation.date | 2023 | |
dc.bibliographicCitation.firstPage | e202214706 | |
dc.bibliographicCitation.issue | 6 | |
dc.bibliographicCitation.volume | 62 | |
dc.contributor.author | Hu, Yuya | |
dc.contributor.author | Sang, Rui | |
dc.contributor.author | Vroemans, Robby | |
dc.contributor.author | Mollaert, Guillaume | |
dc.contributor.author | Razzaq, Rauf | |
dc.contributor.author | Neumann, Helfried | |
dc.contributor.author | Junge, Henrik | |
dc.contributor.author | Franke, Robert | |
dc.contributor.author | Jackstell, Ralf | |
dc.contributor.author | Maes, Bert U. W. | |
dc.contributor.author | Beller, Matthias | |
dc.date.accessioned | 2023-04-04T08:15:20Z | |
dc.date.available | 2023-04-04T08:15:20Z | |
dc.date.issued | 2022 | |
dc.description.abstract | Diesters are of fundamental importance in the chemical industry and are used for many applications, e.g. as plasticizers, surfactants, emulsifiers, and lubricants. Herein, we present a straightforward and efficient method for the selective synthesis of diesters via palladium-catalyzed direct carbonylation of di- or polyols with readily available alkenes. Key-to-success is the use of a specific palladium catalyst with the “built-in-base” ligand L16 providing esterification of all alcohols and a high n/iso ratio. The synthesized diesters were evaluated as potential plasticizers in PVC films by measuring the glass transition temperature (Tg) via differential scanning calorimetry (DSC). | eng |
dc.description.version | publishedVersion | eng |
dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/11880 | |
dc.identifier.uri | http://dx.doi.org/10.34657/10913 | |
dc.language.iso | eng | |
dc.publisher | Weinheim : Wiley-VCH | |
dc.relation.doi | https://doi.org/10.1002/anie.202214706 | |
dc.relation.essn | 1521-3773 | |
dc.relation.ispartofseries | Angewandte Chemie International Edition 62 (2023), Nr. 6 | eng |
dc.relation.issn | 1433-7851 | |
dc.rights.license | CC BY-NC 4.0 Unported | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc/4.0 | |
dc.subject | Carbonylation | eng |
dc.subject | Olefins | eng |
dc.subject | Palladium | eng |
dc.subject | Plasticizers | eng |
dc.subject | Sustainability | eng |
dc.subject.ddc | 540 | |
dc.title | Efficient Synthesis of Novel Plasticizers by Direct Palladium-Catalyzed Di- or Multi-carbonylations | eng |
dc.type | article | |
dc.type | Text | |
dcterms.bibliographicCitation.journalTitle | Angewandte Chemie International Edition | |
tib.accessRights | openAccess | |
wgl.contributor | LIKAT | |
wgl.subject | Chemie | ger |
wgl.type | Zeitschriftenartikel | ger |
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