Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes
dc.bibliographicCitation.firstPage | 12641 | eng |
dc.bibliographicCitation.issue | 1 | eng |
dc.bibliographicCitation.volume | 7 | eng |
dc.contributor.author | Elangovan, Saravanakumar | |
dc.contributor.author | Neumann, Jacob | |
dc.contributor.author | Sortais, Jean-Baptiste | |
dc.contributor.author | Junge, Kathrin | |
dc.contributor.author | Darcel, Christophe | |
dc.contributor.author | Beller, Matthias | |
dc.date.accessioned | 2022-08-10T12:12:55Z | |
dc.date.available | 2022-08-10T12:12:55Z | |
dc.date.issued | 2016 | |
dc.description.abstract | Borrowing hydrogen (or hydrogen autotransfer) reactions represent straightforward and sustainable C-N bond-forming processes. In general, precious metal-based catalysts are employed for this effective transformation. In recent years, the use of earth abundant and cheap non-noble metal catalysts for this process attracted considerable attention in the scientific community. Here we show that the selective N-alkylation of amines with alcohols can be catalysed by defined PNP manganese pincer complexes. A variety of substituted anilines are monoalkylated with different (hetero)aromatic and aliphatic alcohols even in the presence of other sensitive reducible functional groups. As a special highlight, we report the chemoselective monomethylation of primary amines using methanol under mild conditions. | eng |
dc.description.version | publishedVersion | eng |
dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/9974 | |
dc.identifier.uri | http://dx.doi.org/10.34657/9012 | |
dc.language.iso | eng | eng |
dc.publisher | [London] : Nature Publishing Group UK | eng |
dc.relation.doi | https://doi.org/10.1038/ncomms12641 | |
dc.relation.essn | 2041-1723 | |
dc.relation.ispartofseries | Nature Communications 7 (2016), Nr. 1 | eng |
dc.rights.license | CC BY 4.0 Unported | eng |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | eng |
dc.subject | alcohol derivative | eng |
dc.subject | alkanol | eng |
dc.subject | amine | eng |
dc.subject | aniline | eng |
dc.subject | aromatic compound | eng |
dc.subject.ddc | 500 | eng |
dc.title | Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes | eng |
dc.type | article | eng |
dc.type | Text | eng |
dcterms.bibliographicCitation.journalTitle | Nature communications | eng |
tib.accessRights | openAccess | eng |
wgl.contributor | LIKAT | eng |
wgl.subject | Chemie | eng |
wgl.type | Zeitschriftenartikel | eng |
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