Trimethylsilyl Pseudohalide Adducts of GaCl3 and B(C6F5)3

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dc.bibliographicCitation.firstPage1913eng
dc.bibliographicCitation.issue20eng
dc.bibliographicCitation.journalTitleEuropean journal of inorganic chemistryeng
dc.bibliographicCitation.lastPage1920eng
dc.bibliographicCitation.volume2021eng
dc.contributor.authorBläsing, Kevin
dc.contributor.authorBresien, Jonas
dc.contributor.authorMaurer, Steffen
dc.contributor.authorSchulz, Axel
dc.contributor.authorVillinger, Alexander
dc.date.accessioned2022-01-25T09:56:08Z
dc.date.available2022-01-25T09:56:08Z
dc.date.issued2021
dc.description.abstractMe3Si−X (X=CN, N3, OCN, and SCN) was treated with the Lewis acids GaCl3 and B(C6F5)3 in toluene yielding the desired adducts Me3Si−X→GaCl3 and Me3Si−X→B(C6F5)3. All synthesized adducts were isolated and completely characterized including single crystal structure elucidations. The different structures, thermodynamics of formation and charge transfer effects are discussed on the basis of experimental and theoretical data.eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/7912
dc.identifier.urihttps://doi.org/10.34657/6953
dc.language.isoengeng
dc.publisherWeinheim : Wiley-VCHeng
dc.relation.doihttps://doi.org/10.1002/ejic.202100237
dc.relation.essn1099-0682
dc.rights.licenseCC BY 4.0 Unportedeng
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/eng
dc.subject.ddc540eng
dc.subject.otherAdductseng
dc.subject.otherAzideseng
dc.subject.otherCyanateseng
dc.subject.otherCyanideseng
dc.subject.otherPseudohalogenseng
dc.subject.otherRhodanideseng
dc.titleTrimethylsilyl Pseudohalide Adducts of GaCl3 and B(C6F5)3eng
dc.typeArticleeng
dc.typeTexteng
tib.accessRightsopenAccesseng
wgl.contributorLIKATeng
wgl.subjectChemieeng
wgl.typeZeitschriftenartikeleng
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