Tris(tetrahydrofuran-kO)tris[tris(thio-phen-2-yl)methanolato-kO]terbium(III)tetrahydrofuran monosolvate

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inm201170.pdf (772.73 KB)

Date

2011

Authors

Editor

Advisor

Volume

67

Issue

12

Journal

Acta Crystallographica Section E-Structure Reports Online

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Book Title

Publisher

Chester : International Union of Crystallography

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Link to publishers' Version

https://doi.org/10.1107/S160053681104623X

Abstract

In the mononuclear title compound, [Tb(C13H9OS3)3(C4H8O)3]·C4H8O, the lanthanide cation is located on a threefold rotation axis and is surrounded by electron-rich ligands in an approximately octahedral geometry. One of the thienyl groups and the bound THF are disordered with 0.5:0.5 occupancy. The free THF is disordered around the threefold axis.

Description

Keywords

single-crystal X-ray study, T = 132 k, mean sigma(C-C) = 0.006 Å, disorder in main residue, R factor = 0.035, wR factor = 0.085, data-to-parameter ratio = 23.9

Keywords GND

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Publication Type

Article

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publishedVersion

URI

https://doi.org/10.34657/590
 https://oa.tib.eu/renate/handle/123456789/87

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Chemie

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