Enhancement and limits of the selective oxidation of methane to formaldehyde over V-SBA-15: Influence of water cofeed and product decomposition

dc.bibliographicCitation.firstPage106317eng
dc.bibliographicCitation.journalTitleCatalysis Communicationseng
dc.bibliographicCitation.volume155eng
dc.contributor.authorKunkel, Benny
dc.contributor.authorWohlrab, Sebastian
dc.date.accessioned2022-03-24T06:49:05Z
dc.date.available2022-03-24T06:49:05Z
dc.date.issued2021
dc.description.abstractThe possibility of a selective catalytic oxidation of methane to formaldehyde has been known for decades, and positive influences of water added to the reaction mixture and ultra-short contact times have been reported. In the present work, the complexity of interdependencies has been revealed. Specific parameter variations can increase conversion and selectivity of the target product. Surprisingly, formaldehyde formation over VOx species and its decomposition in gas phase were equally dependent on the partial pressure of the added water, so that the sweet spot can only be found by varying the residence time. © 2021 The Author(s)eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/8348
dc.identifier.urihttps://doi.org/10.34657/7386
dc.language.isoengeng
dc.publisherAmsterdam : Elseviereng
dc.relation.doihttps://doi.org/10.1016/j.catcom.2021.106317
dc.relation.issn1566-7367
dc.rights.licenseCC BY-NC-ND 4.0 Unportedeng
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/eng
dc.subject.ddc540eng
dc.subject.ddc660eng
dc.subject.otherFormaldehydeeng
dc.subject.otherMethaneeng
dc.subject.otherSelective oxidationeng
dc.subject.otherV-SBA-15eng
dc.subject.otherWater cofeedeng
dc.titleEnhancement and limits of the selective oxidation of methane to formaldehyde over V-SBA-15: Influence of water cofeed and product decompositioneng
dc.typeArticleeng
dc.typeTexteng
tib.accessRightsopenAccesseng
wgl.contributorLIKATeng
wgl.subjectChemieeng
wgl.typeZeitschriftenartikeleng
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