Growth of LiCoO2 Single Crystals by the TSFZ Method

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dc.bibliographicCitation.firstPage415eng
dc.bibliographicCitation.issue1eng
dc.bibliographicCitation.journalTitleCrystal growth & designeng
dc.bibliographicCitation.lastPage420eng
dc.bibliographicCitation.volume19eng
dc.contributor.authorNakamura, Shigenobu
dc.contributor.authorMaljuk, Andrey
dc.contributor.authorMaruyama, Yuki
dc.contributor.authorNagao, Masanori
dc.contributor.authorWatauchi, Satoshi
dc.contributor.authorHayashi, Takeshi
dc.contributor.authorAnzai, Yutaka
dc.contributor.authorFurukawa, Yasunori
dc.contributor.authorLing, Chris D.
dc.contributor.authorDeng, Guochu
dc.contributor.authorAvdeev, Maxim
dc.contributor.authorBüchner, Bernd
dc.contributor.authorTanaka, Isao
dc.date.accessioned2021-09-27T05:54:07Z
dc.date.available2021-09-27T05:54:07Z
dc.date.issued2018
dc.description.abstractWe have grown LiCoO2 single crystals by the traveling solvent floating zone (TSFZ) growth with Li-rich solvent, having observed the incongruent melting behavior of LiCoO2 between 1100 and 1300 °C. The optimum growth conditions in terms of atmosphere and solvent composition were determined to be Ar flow and an atomic ratio Li/Co 85:15, respectively. The crystals grown using a conventional-mirror-type furnace contained periodic inclusions of a Co-O phase due to the influence of Co-O phase segregation on the stability of the molten zone during growth. By using a tilted-mirror FZ furnace, inclusion-free LiCoO2 crystals of about 5 mm in diameter and 70 mm long were obtained at a tilting angle Î = 10°. The grown crystals were confirmed to be single-domain by neutron Laue diffraction. © 2018 American Chemical Society.eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/6903
dc.identifier.urihttps://doi.org/10.34657/5950
dc.language.isoengeng
dc.publisherWashington, DC : ACS Publ.eng
dc.relation.doihttps://doi.org/10.1021/acs.cgd.8b01503
dc.relation.essn1528-7505
dc.relation.issn1528-7483
dc.rights.licenseACS AuthorChoiceeng
dc.rights.urihttps://pubs.acs.org/page/policy/authorchoice_ccbyncnd_termsofuse.htmleng
dc.subject.ddc540eng
dc.subject.otherChromium compoundseng
dc.subject.otherMirrorseng
dc.subject.otherSingle crystalseng
dc.subject.otherSolventseng
dc.subject.otherGrown crystalseng
dc.subject.otherLaue diffractioneng
dc.subject.otherMelting behavioreng
dc.subject.otherOptimum growth conditionseng
dc.subject.otherSingle domainseng
dc.subject.otherSolvent compositioneng
dc.subject.otherTilting angleeng
dc.subject.otherTraveling-solvent floating-zoneseng
dc.subject.otherLithium compoundseng
dc.titleGrowth of LiCoO2 Single Crystals by the TSFZ Methodeng
dc.typeArticleeng
dc.typeTexteng
tib.accessRightsopenAccesseng
wgl.contributorIFWDeng
wgl.subjectChemieeng
wgl.typeZeitschriftenartikeleng
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