Homopolymerization of ethylene, 1-hexene, styrene and copolymerization of styrene with 1,3-cyclohexadiene using (η5- tetramethylcyclopentadienyl)dimethylsilyl(N-Ar')amido-TiCl2/MAO (Ar'=6-(2-(diethylboryl)phenyl)pyrid-2-yl, biphen-3-yl)

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dc.bibliographicCitation.firstPage567eng
dc.bibliographicCitation.issue1eng
dc.bibliographicCitation.journalTitleMoleculeseng
dc.bibliographicCitation.volume16eng
dc.contributor.authorCamadanli, S.
dc.contributor.authorDecker, U.
dc.contributor.authorKühnel, C.
dc.contributor.authorReinhardt, I.
dc.contributor.authorBuchmeiser, M.R.
dc.date.accessioned2020-09-29T09:09:37Z
dc.date.available2020-09-29T09:09:37Z
dc.date.issued2011
dc.description.abstractThe propensity of a half-sandwich (η55- tetramethylcyclopentadienyl) dimethylsilylamido TiIV-based catalyst bearing an auxiliary diethylboryl-protected pyridyl moiety (Ti-8), activated by methylaluminoxane (MAO) to homopolymerize α-olefins such as ethylene, 1-hexene and styrene as well as to copolymerize styrene with 1,3-cyclohexadiene is described. The reactivity of Ti-8 was investigated in comparison to a 6-(2-(diethylboryl)phenyl)pyrid-2-yl-free analogue (Ti-3).eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://doi.org/10.34657/4375
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/5746
dc.language.isoengeng
dc.publisherBasel : MDPI AGeng
dc.relation.doihttps://doi.org/10.3390/molecules16010567
dc.relation.issn1420-3049
dc.rights.licenseCC BY-NC-SA 3.0 Unportedeng
dc.rights.urihttps://creativecommons.org/licenses/by-nc-sa/3.0/eng
dc.subject.ddc540eng
dc.subject.otherConstrained geometry catalysteng
dc.subject.otherCopolymerizationeng
dc.subject.otherHomopolymerizationeng
dc.subject.otherOlefineng
dc.subject.other1 hexeneeng
dc.subject.other1,3 cyclohexadieneeng
dc.subject.other1,3-cyclohexadieneeng
dc.subject.other1-hexeneeng
dc.subject.otheralkeneeng
dc.subject.othercyclohexene derivativeeng
dc.subject.otherpolymereng
dc.subject.otherstyreneeng
dc.subject.othertitaniumeng
dc.subject.otherarticleeng
dc.subject.othercatalysiseng
dc.subject.otherchemistryeng
dc.subject.othernuclear magnetic resonance spectroscopyeng
dc.subject.otherAlkeneseng
dc.subject.otherCatalysiseng
dc.subject.otherCyclohexeneseng
dc.subject.otherMagnetic Resonance Spectroscopyeng
dc.subject.otherPolymerseng
dc.subject.otherStyreneeng
dc.subject.otherTitaniumeng
dc.titleHomopolymerization of ethylene, 1-hexene, styrene and copolymerization of styrene with 1,3-cyclohexadiene using (η5- tetramethylcyclopentadienyl)dimethylsilyl(N-Ar')amido-TiCl2/MAO (Ar'=6-(2-(diethylboryl)phenyl)pyrid-2-yl, biphen-3-yl)eng
dc.typeArticleeng
dc.typeTexteng
tib.accessRightsopenAccesseng
wgl.contributorIOMeng
wgl.subjectChemieeng
wgl.typeZeitschriftenartikeleng
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