Highly selective visible light-induced Ti–O bond splitting in an ansa-titanocene dihydroxido complex

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dc.bibliographicCitation.firstPage3065eng
dc.bibliographicCitation.issue15eng
dc.bibliographicCitation.journalTitleChemical communications : ChemCommeng
dc.bibliographicCitation.lastPage3068eng
dc.bibliographicCitation.volume51eng
dc.contributor.authorGodemann, Christian
dc.contributor.authorDura, Laura
dc.contributor.authorHollmann, Dirk
dc.contributor.authorGrabow, Kathleen
dc.contributor.authorBentrup, Ursula
dc.contributor.authorJiao, Haijun
dc.contributor.authorSchulz, Axel
dc.contributor.authorBrückner, Angelika
dc.contributor.authorBeweries, Torsten
dc.date.accessioned2022-06-23T12:11:47Z
dc.date.available2022-06-23T12:11:47Z
dc.date.issued2015
dc.description.abstractIrradiation of a substituted ansa-titanocene(IV) dihydroxido complex with visible light induces Ti–O bond dissociation. In contrast to previous studies on structurally similar unbridged complexes, no side reactions are observed and formation of the Ti(III) species is highly selective. The formation of OH radicals was proved using a biradicaloid species.eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/9178
dc.identifier.urihttps://doi.org/10.34657/8216
dc.language.isoengeng
dc.publisherCambridge : Soc.eng
dc.relation.doihttps://doi.org/10.1039/c4cc09733e
dc.relation.essn1364-548X
dc.rights.licenseCC BY 3.0 Unportedeng
dc.rights.urihttps://creativecommons.org/licenses/by/3.0/eng
dc.subject.ddc540eng
dc.subject.otherhydroxyl radicaleng
dc.subject.othertitanium dioxideeng
dc.subject.othertitanoceneeng
dc.subject.otherchelationeng
dc.subject.otherchemical bondeng
dc.subject.otherdissociationeng
dc.subject.otherelectron spin resonanceeng
dc.subject.otherenvironmental temperatureeng
dc.subject.otherirradiationeng
dc.subject.otherlighteng
dc.subject.otherphotodegradationeng
dc.subject.otherpolymerizationeng
dc.subject.otherproton nuclear magnetic resonanceeng
dc.titleHighly selective visible light-induced Ti–O bond splitting in an ansa-titanocene dihydroxido complexeng
dc.typeArticleeng
dc.typeTexteng
tib.accessRightsopenAccesseng
wgl.contributorLIKATeng
wgl.subjectChemieeng
wgl.typeZeitschriftenartikeleng
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