Highly selective visible light-induced Ti–O bond splitting in an ansa-titanocene dihydroxido complex

Simple item page
dc.bibliographicCitation.firstPage3065eng
dc.bibliographicCitation.issue15eng
dc.bibliographicCitation.lastPage3068eng
dc.bibliographicCitation.volume51eng
dc.contributor.authorGodemann, Christian
dc.contributor.authorDura, Laura
dc.contributor.authorHollmann, Dirk
dc.contributor.authorGrabow, Kathleen
dc.contributor.authorBentrup, Ursula
dc.contributor.authorJiao, Haijun
dc.contributor.authorSchulz, Axel
dc.contributor.authorBrückner, Angelika
dc.contributor.authorBeweries, Torsten
dc.date.accessioned2022-06-23T12:11:47Z
dc.date.available2022-06-23T12:11:47Z
dc.date.issued2015
dc.description.abstractIrradiation of a substituted ansa-titanocene(IV) dihydroxido complex with visible light induces Ti–O bond dissociation. In contrast to previous studies on structurally similar unbridged complexes, no side reactions are observed and formation of the Ti(III) species is highly selective. The formation of OH radicals was proved using a biradicaloid species.eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/9178
dc.identifier.urihttps://doi.org/10.34657/8216
dc.language.isoengeng
dc.publisherCambridge : Soc.eng
dc.relation.doihttps://doi.org/10.1039/c4cc09733e
dc.relation.essn1364-548X
dc.relation.ispartofseriesChemical communications : ChemComm 51 (2015), Nr. 15eng
dc.rights.licenseCC BY 3.0 Unportedeng
dc.rights.urihttps://creativecommons.org/licenses/by/3.0/eng
dc.subjecthydroxyl radicaleng
dc.subjecttitanium dioxideeng
dc.subjecttitanoceneeng
dc.subjectchelationeng
dc.subjectchemical bondeng
dc.subjectdissociationeng
dc.subjectelectron spin resonanceeng
dc.subjectenvironmental temperatureeng
dc.subjectirradiationeng
dc.subjectlighteng
dc.subjectphotodegradationeng
dc.subjectpolymerizationeng
dc.subjectproton nuclear magnetic resonanceeng
dc.subject.ddc540eng
dc.titleHighly selective visible light-induced Ti–O bond splitting in an ansa-titanocene dihydroxido complexeng
dc.typearticleeng
dc.typeTexteng
dcterms.bibliographicCitation.journalTitleChemical communications : ChemCommeng
tib.accessRightsopenAccesseng
wgl.contributorLIKATeng
wgl.subjectChemieeng
wgl.typeZeitschriftenartikeleng
Files
Original bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
Highly_selective_visible_light-induced_Ti-O.pdf
Size:
1.75 MB
Format:
Adobe Portable Document Format
Description:
Download
Collections
Chemie