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search.filters.applied.f.access: openAccess × Author: Beller, M. × End date: 2024 × Start date: 2020 × End date: 2014 × Start date: 2013 × DDC: 540 × Type: Text ×

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    (η6-Benzene)(carbonato-κ2O,O') [dicyclohexyl(naphthalen-1-ylmethyl)phosphanejP] ruthenium(II) chloroform trisolvate
    (Chester : International Union of Crystallography, 2014) Gowrisankar, S.; Neumann, H.; Spannenberg, A.; Beller, M.
    The title compound, [Ru(CO3)(η6-C 6H6){(C6H11)2P(CH 2-C10H7)}]-3CHCl3, was synthesized by carbonation of [RuCl2-(η6-C6H 6){(C6H11)2P(CH2C 10H7)}] with NaHCO3in methanol at room temperature. The RuIIatom is surrounded by a benzene ligand, a chelating carbonate group and a phosphane ligand in a piano-stool configuration. The crystal packing is consolidated by C-H⋯O and C-H⋯Cl hydrogen-bonding interactions between adjacent metal complexes and between the complexes and the solvent molecules. The asymmetric unit contains one metal complex and three chloroform solvent molecules of which only one was modelled. The estimated diffraction contributions of the other two strongly disordered chloroform solvent molecules were substracted from the observed diffraction data using the SQUEEZE procedure in PLATON.
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    (η6-Benzene)dichlorido(chlorodicyclohexylphosphane-κp) ruthenium(II) chloroform monosolvate
    (Chester : International Union of Crystallography, 2014) Gowrisankar, S.; Neumann, H.; Spannenberg, A.; Beller, M.
    The title compound, [RuN4(-6-C6H6) (C12H22ClP)]-CHCl3, was prepared by reaction of [RuN 4(-6-C6H6)]2 with chlorodicyclohexyl phosphane in CHCl3 at 323 K under argon. The RuII atom is surrounded by one arene ligand, two Cl atoms and a phosphane ligand in a piano-stool geometry. The phosphane ligand is linked by the P atom, with an Ru-P bond length of 2.3247 (4) Å. Both cyclohexyl rings at the P atom adopt a chair conformation. In the crystal, the RuII complex molecule and the chloroform solvent molecule are linked by a bifurcated C-H⋯(Cl,Cl) hydrogen bond. Intramolecular C-H⋯Cl hydrogen bonds are also observed.
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    Catalytic hydrogenation of carboxylic acid esters, amides, and nitriles with homogeneous catalysts
    (Washington, DC : American Chemical Society, 2014) Werkmeister, S.; Junge, K.; Beller, M.
    This review describes the catalytic reduction of amides, carboxylic acid esters and nitriles with homogeneous catalysts using molecular hydrogen as an environmental friendly reducing agent.
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    Novel ruthenium-catalyst for hydroesterification of olefins with formates
    (London [u.a.] : Royal Society of Chemistry, 2014) Profir, I.; Beller, M.; Fleischer, I.
    An alternative ruthenium-based catalyst for the hydroesterification of olefins with formates is reported. The good activity of our system is ensured by the use of a bidentate P,N-ligand and ruthenium dodecacarbonyl. A range of formates can be used for selective alkoxycarbonylation of aromatic olefins. In addition, the synthesis of selected aliphatic esters is realized. The proposed active ruthenium complex has been isolated and characterized.