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- ItemDifferentialgeometrie im Grossen (hybrid meeting)(Zürich : EMS Publ. House, 2021) Hamenstädt, Ursula; Lang, Urs; Weinkove, BenThe field of classical differential geometry has expanded enormously over the last several decades, helped by the development of tools from neighboring fields such as partial differential equations, complex analysis and geometric topology. In the spirit of the previous meetings in the series, this meeting will bring together researchers from apparently separate subfields of differential geometry, but whose work is linked by common themes. In particular, this meeting will emphasize intrinsic geometric questions motivated by the classification and rigidity of global geometric structures and the interaction of curvature with the underlying geometry and topology.
- ItemSharp phase transition for Cox percolation(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2022) Hirsch, Christian; Jahnel, Benedikt; Muirhead, StephenWe prove the sharpness of the percolation phase transition for a class of Cox percolation models, i.e., models of continuum percolation in a random environment. The key requirements are that the environment has a finite range of dependence and satisfies a local boundedness condition, however the FKG inequality need not hold. The proof combines the OSSS inequality with a coarse-graining construction.
- ItemPhenological model intercomparison for estimating grapevine budbreak date (Vitis vinifera L.) in Europe(Basel : MDPI, 2020) Leolini, Luisa; Costafreda-Aumedes, Sergi; Santos, João A.; Menz, Christoph; Fraga, Helder; Molitor, Daniel; Merante, Paolo; Junk, Jürgen; Kartschall, Thomas; Destrac-Irvine, Agnès; van Leeuwen, Cornelis; Malheiro, Aureliano C.; Eiras-Dias, José; Silvestre, José; Dibari, Camilla; Bindi, Marco; Moriondo, MarcoBudbreak date in grapevine is strictly dependent on temperature, and the correct simulation of its occurrence is of great interest since it may have major consequences on the final yield and quality. In this study, we evaluated the reliability for budbreak simulation of two modeling approaches, the chilling-forcing (CF), which describes the entire dormancy period (endo-and eco-dormancy) and the forcing approach (F), which only describes the eco-dormancy. For this, we selected six phenological models that apply CF and F in dierent ways, which were tested on budbreak simulation of eight grapevine varieties cultivated at dierent latitudes in Europe. Although none of the compared models showed a clear supremacy over the others, models based on CF showed a generally higher estimation accuracy than F where fixed starting dates were adopted. In the latter models, the accurate simulation of budbreak was dependent on the selection of the starting date for forcing accumulation that changes according to the latitude, whereas CF models were independent. Indeed, distinct thermal requirements were found for the grapevine varieties cultivated in Northern and Southern Europe. This implies the need to improve modeling of the dormancy period to avoid under-or over-estimations of budbreak date under dierent environmental conditions. © 2020 by the authors.
- ItemAmbient Hydrogenation and Deuteration of Alkenes Using a Nanostructured Ni-Core-Shell Catalyst(Weinheim : Wiley-VCH, 2021) Gao, Jie; Ma, Rui; Feng, Lu; Liu, Yuefeng; Jackstell, Ralf; Jagadeesh, Rajenahally V.; Beller, MatthiasA general protocol for the selective hydrogenation and deuteration of a variety of alkenes is presented. Key to success for these reactions is the use of a specific nickel-graphitic shell-based core–shell-structured catalyst, which is conveniently prepared by impregnation and subsequent calcination of nickel nitrate on carbon at 450 °C under argon. Applying this nanostructured catalyst, both terminal and internal alkenes, which are of industrial and commercial importance, were selectively hydrogenated and deuterated at ambient conditions (room temperature, using 1 bar hydrogen or 1 bar deuterium), giving access to the corresponding alkanes and deuterium-labeled alkanes in good to excellent yields. The synthetic utility and practicability of this Ni-based hydrogenation protocol is demonstrated by gram-scale reactions as well as efficient catalyst recycling experiments. © 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH
- ItemThermoelectric Properties of N-Type Poly (Ether Ether Ketone)/Carbon Nanofiber Melt-Processed Composites(Basel : MDPI, 2022) Paleo, Antonio Jose; Krause, Beate; Soares, Delfim; Melle-Franco, Manuel; Muñoz, Enrique; Pötschke, Petra; Rocha, Ana MariaThe thermoelectric properties, at temperatures from 30 °C to 100 °C, of melt-processed poly(ether ether ketone) (PEEK) composites prepared with 10 wt.% of carbon nanofibers (CNFs) are discussed in this work. At 30 °C, the PEEK/CNF composites show an electrical conductivity (σ) of ~27 S m−1 and a Seebeck coefficient (S) of −3.4 μV K−1, which means that their majority charge carriers are electrons. The origin of this negative Seebeck is deduced because of the impurities present in the as-received CNFs, which may cause sharply varying and localized states at approximately 0.086 eV above the Fermi energy level (EF) of CNFs. Moreover, the lower S, in absolute value, found in PEEK/CNF composites, when compared with the S of as-received CNFs (−5.3 μV K−1), is attributed to a slight electron withdrawing from the external layers of CNFs by the PEEK matrix. At temperatures from 30 °C to 100 °C, the σ (T) of PEEK/CNF composites, in contrast to the σ (T) of as-received CNFs, shows a negative temperature effect, understood through the 3D variable-range hopping (VRH) model, as a thermally activated hopping mechanism across a random network of potential wells. Moreover, their nonlinear S (T) follows the same behavior reported before for polypropylene composites melt-processed with similar CNFs at the same interval of temperatures.
- ItemA self-consistent dynamical model of the Milky Way disc adjusted to Gaia data(Les Ulis : EDP Sciences, 2022) Robin, A.C.; Bienaymé, O.; Salomon, J.B.; Reylé, C.; Lagarde, N.; Figueras, F.; Mor, R.; Fernández-Trincado, J.G.; Montillaud, J.Context. Accurate astrometry achieved by Gaia for many stars in the Milky Way provides an opportunity to reanalyse the Galactic stellar populations from a large and homogeneous sample and to revisit the Galaxy gravitational potential. Aims. This paper shows how a self-consistent dynamical model can be obtained by fitting the gravitational potential of the Milky Way to the stellar kinematics and densities from Gaia data. Methods. We derived a gravitational potential using the Besancon Galaxy Model, and computed the disc stellar distribution functions based on three integrals of motion (E, Lz, I3) to model stationary stellar discs. The gravitational potential and the stellar distribution functions are built self-consistently, and are then adjusted to be in agreement with the kinematics and the density distributions obtained from Gaia observations. A Markov chain Monte Carlo (MCMC) is used to fit the free parameters of the dynamical model to Gaia parallax and proper motion distributions. The fit is done on several sets of Gaia data, mainly a subsample of the GCNS (Gaia catalogue of nearby stars to 100 pc) with G< 17, together with 26 deep fields selected from eDR3, widely spread in longitudes and latitudes. Results. We are able to determine the velocity dispersion ellipsoid and its tilt for subcomponents of different ages, both varying with R and z. The density laws and their radial scale lengths for the thin and thick disc populations are also obtained self-consistently. This new model has some interesting characteristics that come naturally from the process, such as a flaring thin disc. The thick disc is found to present very distinctive characteristics from the old thin disc, both in density and kinematics. This lends significant support to the idea that thin and thick discs were formed in distinct scenarios, as the density and kinematics transition between them is found to be abrupt. The dark matter halo is shown to be nearly spherical. We also derive the solar motion with regards to the Local Standard of Rest (LSR), finding U· = 10.79 ± 0.56 km s-1, V· = 11.06 ± 0.94 km s-1, and W· = 7.66 ± 0.43 km s-1, in close agreement with recent studies. Conclusions. The resulting fully self-consistent gravitational potential, still axisymmetric, is a good approximation of a smooth mass distribution in the Milky Way and can be used for further studies, including finding streams, substructures, and to compute orbits for real stars in our Galaxy.
- ItemLi+/H+ exchange of Li7La3Zr2O12 single and polycrystals investigated by quantitative LIBS depth profiling(Cambridge : Royal Society of Chemistry, 2022) Smetaczek, Stefan; Limbeck, Andreas; Zeller, Veronika; Ring, Joseph; Ganschow, Steffen; Rettenwander, Daniel; Fleig, JürgenLi7La3Zr2O12 (LLZO) garnets are highly attractive to be used as solid electrolyte in solid-state Li batteries. However, LLZO suffers from chemical interaction with air and humidity, causing Li+/H+ exchange with detrimental implication on its performance, processing and scalability. To better understand the kinetics of the detrimental Li+/H+ exchange and its dependence on microstructural features, accelerated Li+/H+ exchange experiments were performed on single crystalline and polycrystalline LLZO, exposed for 80 minutes to 80 °C hot water. The resulting chemical changes were quantified by analytical methods, i.e. inductively coupled plasma optical emission spectroscopy (ICP-OES) and laser induced breakdown spectroscopy (LIBS). From the time dependence of the Li+ enrichment in the water, measured by ICP-OES, a bulk interdiffusion coefficient of Li+/H+ could be determined (7 × 10−17 m2 s−1 at 80 °C). Depth dependent concentrations were obtained from the LIBS data for both ions after establishing a calibration method enabling not only Li+ but also H+ quantification in the solid electrolyte. Short interdiffusion lengths in the 1 μm range are found for the single crystalline Ga:LLZO, in accordance with the measured bulk diffusion coefficient. In polycrystalline Ta:LLZO, however, very long diffusion tails in the 20 μm range and ion exchange fractions up to about 70% are observed. Those are attributed to fast ion interdiffusion along grain boundaries. The severe compositional changes also strongly affect the electrical properties measured by impedance spectroscopy. This study highlights that microstructural effects may be decisive for the Li+/H+ ion exchange kinetics of LLZO.
- ItemProximity array device: a novel photon detector working in long wavelengths(Basel : MDPI AG, 2020) Rezvani, S. Javad; Di Gioacchino, Daniele; Gatti, Claudio; Ligi, Carlo; Guidi, Mariangela Cestelli; Cibella, Sara; Fretto, Matteo; Poccia, Nicola; Lupi, Stefano; Marcelli, AugustoWe present here an innovative photon detector based on the proximity junction array device (PAD) working at long wavelengths. We show that the vortex dynamics in PAD undergoes a transition from a Mott insulator to a vortex metal state by application of an external magnetic field. The PAD also evidences a Josephson I-V characteristic with the external field dependent tunneling current. At high applied currents, we observe a dissipative regime in which the vortex dynamics is dominated by the quasi-particle contribution from the normal metal. The PAD has a relatively high photo-response even at frequencies below the expected characteristic frequency while, its superconducting properties such as the order parameter and the Josephson characteristic frequency can be modulated via external fields to widen the detection band. This device represents a promising and reliable candidate for new high-sensitivity long-wavelength detectors. © 2020 by the authors. Licensee MDPI, Basel, Switzerland.
- ItemPlasma‐treated flammulina velutipes‐derived extract showed anticancer potential in human breast cancer cells(Basel : MDPI, 2020) Mitra, Sarmistha; Bhartiya, Pradeep; Kaushik, Neha; Nguyen, Linh Nhat; Wahab, Rizwan; Bekeschus, Sander; Choi, Eun Ha; Kaushik, Nagendra KumarNatural products with medicinal properties are among alternative therapies of interest due to their high body tolerance. We aimed to determine whether nonthermal gas plasma could enhance the medicinal value of Flammulina velutipes mushrooms. Generated gas plasma was characterized by its emission spectrum in ambient air, pH, temperature, and H2O2 and NOx concentrations after exposure for various periods. Phenolic and flavonoid contents in the extracts were measured using antioxidant assays and Fourier transform infrared and ultraviolet‐visible spectroscopy. We analyzed the effects of the plasma‐treated mushroom‐derived extracts against breast carcinoma using the MCF7 and MDA‐MB231 cell lines. The extracts significantly and concentration dependently inhibited the growth of breast cancer cells without inducing toxicity in normal MCF10A cells, and induced apoptosis via oxidative stress, evidenced by DNA damage (γ‐ H2AX foci formation), and increased the population of MCF7 breast cancer cells arrested in the G2/M phase of the cell cycle. The extracts also induced mitochondrion‐mediated apoptosis of MCF7 cells through cytochrome c release and caspase cleavage activity. The plasma improved the biological activity of mushrooms by increasing their phenolic compounds that prevented the growth of breast cancer cells in vitro. © 2020 by the authors. Licensee MDPI, Basel, Switzerland.
- ItemAutomated and rapid identification of multidrug resistant Escherichia coli against the lead drugs of acylureidopenicillins, cephalosporins, and fluoroquinolones using specific Raman marker bands(Weinheim : Wiley-VCH-Verl., 2020) Götz, Theresa; Dahms, Marcel; Kirchhoff, Johanna; Beleites, Claudia; Glaser, Uwe; Bohnert, Jürgen A.; Pletz, Mathias W.; Popp, Jürgen; Schlattmann, Peter; Neugebauer, UteA Raman-based, strain-independent, semi-automated method is presented that allows the rapid (<3 hours) determination of antibiotic susceptibility of bacterial pathogens isolated from clinical samples. Applying a priori knowledge about the mode of action of the respective antibiotic, we identified characteristic Raman marker bands in the spectrum and calculated batch-wise weighted sum scores from standardized Raman intensity differences between spectra of antibiotic exposed and nonexposed samples of the same strains. The lead substances for three relevant antibiotic classes (fluoroquinolone ciprofloxacin, third-generation cephalosporin cefotaxime, ureidopenicillin piperacillin) against multidrug-resistant Gram-negative bacteria (MRGN) revealed a high sensitivity and specificity for the susceptibility testing of two Escherichia coli laboratory strains and 12 clinical isolates. The method benefits from the parallel incubation of control and treated samples, which reduces the variance due to alterations in cultivation conditions and the standardization of differences between batches leading to long-term comparability of Raman measurements. © 2020 The Authors. Journal of Biophotonics published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim