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- ItemQuasi-static and dynamic deformation behaviour of Zr-based bulk metallic glass(Milton Park : Taylor & Francis, 2013) Nekouie, V.; Kühn, U.; Roy, A.; Silberschmidt, V.Nano- and micro-indentation studies were carried out to characterise a plasticity mechanism through the evolution of localised shear bands that drive material's deformation at sub-micron length scale. Initial deformation of Zr-based bulk metallic glass (BMG) was investigated with nanoindentation tests using a spherical indenter. The indentation cycle reflects an elastic deformation with the yielding load of approx. 3 mN. For designed cycling indentation, hardening and softening phenomena were observed in nano- and micro-indentations, respectively. High-precision dynamic mechanical relaxation measurements were performed using a Dynamic Mechanical Analyzer (DMA), on decreasing frequency from 160 Hz to 0.1 Hz. A mechanical response of the BMG surface to a concentrated impact load was also studied. The obtained results indicated that the studied Zr-based BMG behaved as an elastic-perfectly plastic material at macroscale with discrete plasticity events at smaller length scales.
- ItemAmyloids: From molecular structure to mechanical properties(Amsterdam [u.a.] : Elsevier, 2013) Schleeger, M.; Vandenakker, C.C.; Deckert-Gaudig, T.; Deckert, V.; Velikov, K.P.; Koenderink, G.; Bonn, M.Many proteins of diverse sequence, structure and function self-assemble into morphologically similar fibrillar aggregates known as amyloids. Amyloids are remarkable polymers in several respects. First of all, amyloids can be formed from proteins with very different amino acid sequences; the common denominator is that the individual proteins constituting the amyloid fold predominantly into a β-sheet structure. Secondly, the formation of the fibril occurs through non-covalent interactions between primarily the β-sheets, causing the monomers to stack into fibrils. The fibrils are remarkably robust, considering that the monomers are bound non-covalently. Finally, a common characteristic of fibrils is their unbranched, straight, fiber-like structure arising from the intertwining of the multiple β-sheet filaments. These remarkably ordered and stable nanofibrils can be useful as building blocks for protein-based functional materials, but they are also implicated in severe neurodegenerative diseases. The overall aim of this article is to highlight recent efforts aimed at obtaining insights into amyloid proteins on different length scales. Starting from molecular information on amyloids, single fibril properties and mechanical properties of networks of fibrils are described. Specifically, we focus on the self-assembly of amyloid protein fibrils composed of peptides and denatured model proteins, as well as the influence of inhibitors of fibril formation. Additionally, we will demonstrate how the application of recently developed vibrational spectroscopic techniques has emerged as a powerful approach to gain spatially resolved information on the structure-function relation of amyloids. While spectroscopy provides information on local molecular conformations and protein secondary structure, information on the single fibril level has been developed by diverse microscopic techniques. The approaches to reveal basic mechanical properties of single fibrils like bending rigidity, shear modulus, ultimate tensile strength and fracture behavior are illustrated. Lastly, mechanics of networks of amyloid fibrils, typically forming viscoelastic gels are outlined, with a focus on (micro-) rheological properties. The resulting fundamental insights are essential for the rational design of novel edible and biodegradable protein-based polymers, but also to devise therapeutic strategies to combat amyloid assembly and accumulation during pathogenic disorders.
- ItemCorrosion Fatigue Studies on a Bulk Glassy Zr-Based Alloy under Three-Point Bending(Lausanne : Frontiers Media, 2017-1-9) Grell, Daniel; Wilkin, Yannic; Gostin, Petre F.; Gebert, Annett; Kerscher, EberhardCorrosion fatigue (CF) tests were carried out on bulk glassy Zr52.5Cu17.9Al10Ni14.6Ti5 (Vitreloy 105) samples under load-controlled three-point bending conditions with a load ratio of R = 0.1 in 0.01 M Na2SO4 + 0.01 M NaCl electrolyte. During cyclic testing, the bar-shaped specimens were polarized in situ at constant potentials and the current was monitored. Three different anodic potentials within the interval between the pitting potential EP and the repassivation potential ER and three different load amplitudes were applied. In some cases, in situ microscopic observations revealed the formation of black corrosion products in the vicinity of the crack tip during anodic polarization. Fractographic analysis revealed a clear distinction between two modes of crack growth characterized by smooth dissolution induced regions on the one hand and slim fast fracture areas on the other hand. Both alternating features contributed to a broad-striated CF fracture surface. Moreover, further fatigue tests were carried out under free corrosion conditions yielding additional information on crack initiation and crack propagation period by means of the open circuit potential (OCP) changes. Thereby, a slight increase in OCP was detected after rupture of the passive layer due to bare metal exposed to the electrolyte. The electrochemical response increased continuously according to stable crack propagation until fracture occurred. Finally, the fracture surfaces of the CF samples were investigated by energy dispersive X-ray with the objective of analyzing the elemental distribution after anodic dissolution. Interestingly, anodic polarization at a near repassivation potential of −50 mV vs. saturated calomel electrode (SCE), which commands a constant electric potential of E = 0.241 V vs. standard hydrogen electrode (SHE), led to favorable effects on the fatigue lifetime. In conclusion, all results are conflated to a CF model for bulk glassy Vitreloy 105 under anodic polarization in chloride-containing electrolyte and compared to the previously proposed stress corrosion mechanisms under similar conditions. © 2017 Grell, Wilkin, Gostin, Gebert and Kerscher.
- ItemCatastrophic stress corrosion failure of Zr-base bulk metallic glass through hydrogen embrittlement(Amsterdam [u.a.] : Elsevier Science Amsterdam [u.a.] : Elsevier Science, 2019) Geissler, D.; Uhlemann, M.; Gebert, A.Zr-base bulk metallic glasses (BMG) are prone to pitting corrosion in halide containing solutions and also stress corrosion cracking (SCC) is often interpreted in this context. This work presents in situ SCC experiments on notched Zr52.5Cu17.9Ni14.6Al10Ti5 (at.%) BMG bars under 3-point bending in dilute NaCl solution. They show that pitting corrosion is only the initiating process. The pitted areas have a lower local corrosion potential and the reaction of Zr4+ to zirconyl ions in solution produces H+ that can be reduced and absorbed in the local acidic environment. So, hydrogen embrittlement causes the observed catastrophic failure and peculiar fracture surface characteristics. © 2019 The Authors
- ItemDetection of fractures of hand and forearm in whole-body CT for suspected polytrauma in intubated patients(London : BioMed Central, 2020) Münn, F.; Laun, R.A.; Asmus, A.; Bülow, R.; Bakir, S.; Haralambiev, L.; Eisenschenk, A.; Kim, S.Background: The aim of this study was to evaluate the potential of whole-body CT for diagnosis of hand and forearm fractures in intubated patients with suspected polytrauma. Methods: We performed a retrospective analysis on data collected from two trauma centres in Germany, including demographics, ISS, clinical symptoms, depiction in whole-body CT, and time to diagnosis. Results: Out of 426 patients included in the study, 66 (15.5%) suffered a hand or forearm fracture. The total number of fractures was 132, the whole-body CT report mentioned 98 (74.2%). 16 (12,1%) fractures of 12 patients were diagnosed later than 24 h after admission. Late diagnoses of fractures of the hand occurred more often if the hand was not fully included in the CT scan field. The sensitivity of whole-body CT for cases with fractures of hand and/or forearm with full inclusion of the corresponding area in the scan field was 80.2%. Conclusions: This study shows that whole-body CT is a valuable diagnostic tool for hand fractures in polytrauma patients. Hands should be evaluated regardless of clinical presentation in intubated patients after suspected polytrauma if they are included in the whole-body CT. © 2020 The Author(s).
- ItemDetection of missed fractures of hand and forearm in whole-body CT in a blinded reassessment(London : BioMed Central, 2021) Kim, S.; Goelz, L.; Münn, F.; Kim, D.; Millrose, M.; Eisenschenk, A.; Thelen, S.; Lautenbach, M.Background: We examined the visibility of fractures of hand and forearm in whole-body CT and its influence on delayed diagnosis. This study is based on a prior study on delayed diagnosis of fractures of hand and forearm in patients with suspected polytrauma. Methods: Two blinded radiologists examined CT-scans of patients with fractures of hand or forearm that were diagnosed later than 24 h after admission and control cases with unremarkable imaging of those areas. They were provided with clinical information that was documented in the admission report and were asked to examine forearm and hands. After unblinding, the visibility of fractures was determined. We examined if time of admission or slice thickness was a factor for late or missed diagnoses. Results: We included 72 known fractures in 36 cases. Of those 65 were visible. Sixteen visible fractures were diagnosed late during hospital stay. Eight more fractures were detected on revision by the radiologists. Both radiologists missed known fractures and found new fractures that were not reported by the other. Missed and late diagnoses of fractures occurred more often around 5 pm and 1 am. Slice thickness was not significantly different between fractures and cases with fractures found within 24 h and those found later. Conclusions: The number of late diagnosis or completely missed fractures of the hand and forearm may be reduced by a repeated survey of WBCT with focus on the extremities in patients with suspected polytrauma who are not conscious. Level of evidence: III © 2021, The Author(s).
- ItemA numerical sensitivity study of how permeability, porosity, geological structure, and hydraulic gradient control the lifetime of a geothermal reservoir(Göttingen : Copernicus Publ., 2019) Bauer, Johanna F.; Krumbholz, Michael; Luijendijk, Elco; Tanner, David C.Geothermal energy is an important and sustainable resource that has more potential than is currently utilized. Whether or not a deep geothermal resource can be exploited, mostly depends on, besides temperature, the utilizable reservoir volume over time, which in turn largely depends on petrophysical parameters. We show, using over 1000 (n=1027) 4-D finite-element models of a simple geothermal doublet, that the lifetime of a reservoir is a complex function of its geological parameters, their heterogeneity, and the background hydraulic gradient (BHG). In our models, we test the effects of porosity, permeability, and BHG in an isotropic medium. Furthermore, we simulate the effect of permeability contrast and anisotropy induced by layering, fractures, and a fault. We quantify the lifetime of the reservoir by measuring the time to thermal breakthrough, i.e. how many years pass before the temperature of the produced fluid falls below the 100 ∘C threshold. The results of our sensitivity study attest to the positive effect of high porosity; however, high permeability and BHG can combine to outperform the former. Particular configurations of all the parameters can cause either early thermal breakthrough or extreme longevity of the reservoir. For example, the presence of high-permeability fractures, e.g. in a fault damage zone, can provide initially high yields, but it channels fluid flow and therefore dramatically restricts the exploitable reservoir volume. We demonstrate that the magnitude and orientation of the BHG, provided permeability is sufficiently high, are the prime parameters that affect the lifetime of a reservoir. Our numerical experiments show also that BHGs (low and high) can be outperformed by comparatively small variations in permeability contrast (103) and fracture-induced permeability anisotropy (101) that thus strongly affect the performance of geothermal reservoirs.
- ItemX-ray computed tomography investigation of structures in Opalinus Clay fromlarge-scale to small-scale after mechanical testing(Göttingen : Copernicus Publ., 2016) Kaufhold, Annette; Halisch, Matthias; Zacher, Gerhard; Kaufhold, StephanIn the past years X-ray computed tomography (CT) has became more and more common for geoscientific applications and is used from the µm-scale (e.g. for investigations of microfossils or pore-scale structures) up to the dm-scale (full drill cores or soil columns). In this paper we present results from CT imaging and mineralogical investigations of an Opalinus Clay core on different scales and different regions of interest, emphasizing especially the 3-D evaluation and distribution of cracks and their impact on mechanical testing of such material. Enhanced knowledge of the testing behaviour of the Opalinus Clay is of great interest, especially since this material is considered for a long-term radioactive waste disposal and storage facility in Switzerland. Hence, results are compared regarding the mineral (i.e. phase) contrast resolution, the spatial resolution, and the overall scanning speed. With this extensive interdisciplinary scale-down approach it has been possible to characterize the general fracture propagation in comparison to mineralogical and textural features of the Opalinus Clay. Additionally, and as far as we know, a so-called mylonitic zone, located at an intersect of two main fractures, has been observed for the first time for an experimentally deformed Opalinus sample. The multi-scale results are in good accordance to data from naturally deformed Opalinus Clay samples, which enables us to perform systematical research under controlled laboratory conditions. Accompanying 3-D imaging greatly enhances the capability of data interpretation and assessment of such a material.
- ItemElectric resistivity and seismic refraction tomography: a challenging joint underwater survey at Äspö Hard Rock Laboratory(Göttingen : Copernicus Publ., 2017) Ronczka, Mathias; Hellman, Kristofer; Günther, Thomas; Wisén, Roger; Dahlin, TorleifTunnelling below water passages is a challenging task in terms of planning, pre-investigation and construction. Fracture zones in the underlying bedrock lead to low rock quality and thus reduced stability. For natural reasons, they tend to be more frequent at water passages. Ground investigations that provide information on the subsurface are necessary prior to the construction phase, but these can be logistically difficult. Geophysics can help close the gaps between local point information by producing subsurface images. An approach that combines seismic refraction tomography and electrical resistivity tomography has been tested at the Äspö Hard Rock Laboratory (HRL). The aim was to detect fracture zones in a well-known but logistically challenging area from a measuring perspective. The presented surveys cover a water passage along part of a tunnel that connects surface facilities with an underground test laboratory. The tunnel is approximately 100 m below and 20 m east of the survey line and gives evidence for one major and several minor fracture zones. The geological and general test site conditions, e.g. with strong power line noise from the nearby nuclear power plant, are challenging for geophysical measurements. Co-located positions for seismic and ERT sensors and source positions are used on the 450 m underwater section of the 700 m profile. Because of a large transition zone that appeared in the ERT result and the missing coverage of the seismic data, fracture zones at the southern and northern parts of the underwater passage cannot be detected by separated inversion. Synthetic studies show that significant three-dimensional (3-D) artefacts occur in the ERT model that even exceed the positioning errors of underwater electrodes. The model coverage is closely connected to the resolution and can be used to display the model uncertainty by introducing thresholds to fade-out regions of medium and low resolution. A structural coupling cooperative inversion approach is able to image the northern fracture zone successfully. In addition, previously unknown sedimentary deposits with a significantly large thickness are detected in the otherwise unusually well-documented geological environment. The results significantly improve the imaging of some geologic features, which would have been undetected or misinterpreted otherwise, and combines the images by means of cluster analysis into a conceptual subsurface model.
- ItemTwo-dimensional numerical investigations on the termination of bilinear flow in fractures(Göttingen : Copernicus Publ., 2013) Ortiz R., A.E.; Jung, R.; Renner, J.Bilinear flow occurs when fluid is drained from a permeable matrix by producing it through an enclosed fracture of finite conductivity intersecting a well along its axis. The terminology reflects the combination of two approximately linear flow regimes: one in the matrix with flow essentially perpendicular to the fracture, and one along the fracture itself associated with the non-negligible pressure drop in it. We investigated the characteristics, in particular the termination, of bilinear flow by numerical modeling allowing for an examination of the entire flow field without prescribing the flow geometry in the matrix. Fracture storage capacity was neglected relying on previous findings that bilinear flow is associated with a quasi-steady flow in the fracture. Numerical results were generalized by dimensionless presentation. Definition of a dimensionless time that, other than in previous approaches, does not use geometrical parameters of the fracture permitted identifying the dimensionless well pressure for the infinitely long fracture as the master curve for type curves of all fractures with finite length from the beginning of bilinear flow up to fully developed radial flow. In log–log scale the master curve's logarithmic derivative initially follows a 1/4-slope straight line (characteristic for bilinear flow) and gradually bends into a horizontal line (characteristic for radial flow) for long times. During the bilinear flow period, isobars normalized to well pressure propagate with the fourth and second root of time in fracture and matrix, respectively. The width-to-length ratio of the pressure field increases proportional to the fourth root of time during the bilinear period, and starts to deviate from this relation close to the deviation of well pressure and its derivative from their fourth-root-of-time relations. At this time, isobars are already significantly inclined with respect to the fracture. The type curves of finite fractures all deviate counterclockwise from the master curve instead of clockwise or counterclockwise from the 1/4-slope straight line as previously proposed. The counterclockwise deviation from the master curve was identified as the arrival of a normalized isobar reflected at the fracture tip 16 times earlier. Nevertheless, two distinct regimes were found in regard to pressure at the fracture tip when bilinear flow ends. For dimensionless fracture conductivities TD < 1, a significant pressure increase is not observed at the fracture tip until bilinear flow is succeeded by radial flow at a fixed dimensionless time. For TD > 10, the pressure at the fracture tip has reached substantial fractions of the associated change in well pressure when the flow field transforms towards intermittent formation linear flow at times that scale inversely with the fourth power of dimensionless fracture conductivity. Our results suggest that semi-log plots of normalized well pressure provide a means for the determination of hydraulic parameters of fracture and matrix after shorter test duration than for conventional analysis.