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Author: Müller, B.H. × End date: 2009 × Start date: 2000 × Subject: Chemistry ×

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Now showing 1 - 5 of 5
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    Diacetonitrile[N,N′-bis(2,6-diisopropyl-phenyl)ethane-1,2-diimine] dichloridochromium(II) acetonitrile solvate
    (Chester : International Union of Crystallography, 2009) Peitz, S.; Peulecke, N.; Müller, B.H.; Spannenberg, A.; Rosenthal, U.
    The title compound, [CrCl2(CH3CN)2(C 26H36N2)]·CH3CN, was synthesized by the reaction of CrCl2(THF)2 with N,N′-bis-(2,6- diisopropyl-phen-yl)ethane-1,2-diimine in dichloro-methane/acetonitrile. The chromium center is coordinated by two N atoms of the chelating diimine ligand, two chloride ions in a trans configuration with respect to each other, and by two N atoms of two acetonitrile mol-ecules in a distorted octa-hedral geometry.
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    1,1,2,2-Tetra-phenyl-15-diphosphane 1-sulfide
    (Chester : International Union of Crystallography, 2009) Aluri, B.R.; Peitz, S.; Wöhl, A.; Peulecke, N.; Müller, B.H.; Spannenberg, A.; Rosenthal, U.
    In the title mol-ecule, C24H20P2S, the P - P bond length is 2.2263 (5) Å. The two phenyl rings attached to the three- and five-coordinated P atoms, respectively, form dihedral angles of 56.22 (5) and 71.74 (5)°.
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    Bis[N,N′-bis-(2,6-diisopropylphenyl)ethane-1,2-diimine] -1κ2 N,N′;2κ2 N,N′-tri - Trichlorido-1:2κ6 Cl:Clchlorido-1Cltetrahydrofuran- 2Odichromium(II) dichloromethane 4.5-solvate
    (Chester : International Union of Crystallography, 2009) Peitz, S.; Peulecke, N.; Müller, B.H.; Spannenberg, A.; Rosenthal, U.
    In the mol-ecular structure of the title compound, [Cr2Cl4(C 26H36N2)2(C4H8O)] ·4.5CH2Cl2, the two CrII centers are bridged by three Cl atoms, forming a dinuclear complex. Each CrII center is coordinated by one chelating bis-(2,6-diisopropyl-phen-yl)ethane-1,2-diimine ligand via both N atoms. An additional chloride ion binds to one chromium center, whereas an additional tetra-hydro-furan mol-ecule coordinates to the second CrII center. The coordination geometry at each CrII center can be best described as distorted octa-hedral.
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    [N,N-Bis(diphenyl­phosphino)isopropyl­amine]dibromidonickel(II)
    (Chester : International Union of Crystallography, 2009) Hapke, M.; Wöhl, A.; Peitz, S.; Müller, B.H.; Spannenberg, A.; Rosenthal, U.
    The title compound, [NiBr2(C27H27NP2)], was synthesized by the reaction of NiBr2(dme) (dme is 1,2-dimethoxy-ethane) with N,N-bis-(diphenyl-phosphino)isopropyl-amine in methanol/tetra-hydro-furan. The nickel(II) center is coordinated by two P atoms of the chelating PNP ligand, PH2PN(iPr)PPH2, and two bromide ions in a distorted square-planar geometry.
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    Crystal structure of tris[(diphenylphosphino)methylene)- diphenylphosphoranylmethyl]yttrium diethyl ether monosolvate, [Y{P(C6H5)2CHP(C6H5)2CH2}3] (C2H5)2O
    (München : R. Oldenbourg Verlag GmbH, 2005) Spannenberg, A.; Müller, B.H.; Rosenthal, U.
    C82H79OP6Y, monoclinic, P12/cl (no. 13), a = 24.392(5) Å,b= 12.632(2) Å, c = 23.709(5) Å, β = 100.97°, V = 7171.8 Å3, Z = 4, Rgt(F) = 0.054, wRref(F2) = 0.112, T = 200 K.