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Capillarity problems with nonlocal surface tension energies
2016, Maggi, Francesco, Valdinoci, Enrico
A dynamic large deviations principle for a countable reaction network including coagulation-fragmentation models is proved. The rate function is represented as the infimal cost of the reaction fluxes and a minimiser for this variational problem is shown to exist. A weak reversibility condition is used to control the boundary behaviour and to guarantee a representation for the optimal fluxes via a Lagrange multiplier that can be used to construct the changes of measure used in standard tilting arguments. Reflecting the pure jump nature of the approximating processes, their paths are treated as elements of a BV function space.
Asymptotic expansions of the contact angle in nonlocal capillarity problems
2016, Dipierro, Serena, Maggi, Francesco, Valdinoci, Enrico
We consider a family of nonlocal capillarity models, where surface tension is modeled by exploiting a family of fractional interaction kernels The fractional Young's law (contact angle condition) predicted by these models coincides, in the limit, with the classical Young's law determined by the Gauss free energy. Here we refine this asymptotics by showing that, for s close to 1, the fractional contact angle is always smaller than its classical counterpart when the relative adhesion coefficient is negative, and larger if it is positive. In addition, we address the asymptotics of the fractional Young's law in the limit case s close to 0 of interaction kernels with heavy tails. Interestingly, forsmall s, the dependence of the contact angle from the relative adhesion coefficient becomes linear.