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The Effect of Boron Content on Wetting Kinetics in Si-B Alloy/h-BN System

2019, Polkowski, Wojciech, Sobczak, Natalia, Bruzda, Grzegorz, Nowak, Rafał, Giuranno, Donatella, Kudyba, Artur, Polkowska, Adelajda, Pajor, Krzysztof, Kozieł, Tomasz, Kaban, Ivan

In this work, the effect of boron content on the high-temperature wetting behavior in the Si-B alloy/h-BN systems was experimentally examined. For this reason, hypoeutectic, eutectic and hypereutectic Si-B alloys (Si-1B, Si-3.2B and Si-5.7B wt.%, respectively) were produced by electric arc melting method and then subjected to sessile drop/contact heating experiments with polycrystalline h-BN substrates, at temperatures up to 1750 °C. Similar to pure Si/h-BN system, wetting kinetics curves calculated on a basis of in situ recorded drop/substrate images point toward non-wetting behavior of all selected Si-B alloy/h-BN couples. The highest contact angle values of ~ 150° were obtained for hypoeutectic and eutectic Si-B alloys in the whole examined temperature range. © 2018, The Author(s).