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Crystal structure of (2S,4S,7S)-7,7-dichloro-4-(1-chloro-1-methylethyl)-1- (2,2,2-trichloroethyl)bicyclo[4.1.0]heptane, C12H16Cl 6
C12H16Cl6, orthorhombic, P2 12121 (no. 19), a = 6.0742(3) Å, b = 9.7189(6) Å, c = 26.700(1) Å, V = 1576.2 Å3, Z = 4, Rgt(F) = 0.019, wRref(F2) = 0.045, T= 200 K. © by Oldenbourg Wissenschaftsverlag.
Crystal structure of (η4-cycloocta-1,5-dien)-N-(2- (diphenylphosphinooxy)-3-(naphthalen-1-yloxy)propyl)-N-(pentan-3-yl)-1, 1-diphenylphosphinamine-rhodium(I) tetrafluoroborate, [Rh(C8H 12)(C42H43NO2P2)][BF 4]
C50H55BF4NO2P2Rh, monoclinic, P1211 (no. 4), a = 12.722(3) Å, b = 15.248(3) Å, c = 12.818(3) Å, β = 115.80(3)°, V = 2238.7 Å3, Z = 2, Rgt(F) = 0.036, wRref(F 2) = 0.079, T = 200 K. © by Oldenbourg Wissenschaftsverlag.
Crystal structure of bis(π-allylvalencene)dichlorodipalIadium, [PdCl(C15H23)]2
C30H46Cl2Pd2, monoclinic, Cl21 (no. 5), a = 22.0083(6) Å, b = 6.1827(2) Å, c = 21.5654(7) Å, β = 91.252(2)°, V= 2933.7 Å3, Z = 4, Rgr(F) = 0.019, wRref(F2) = 0.039, T = 200K. © by Oldenbourg Wissenschaftsverlag, München.
Refinement of the crystal structure of holmium tetranickel boride, HoNi4B
BHoNi4, hexagonal, P6/mmm (No. 191), a = 4.9696(4) Å, c = 6.9419(5) Å, V= 148.5 Å3, Z= 2, ρm = 9.13(1) g·cm-3, R(P) = 0.072, wR(P) = 0.099, R(I) = 0.065, T= 300 K.
Diacetonitrile[N,N′-bis(2,6-diisopropyl-phenyl)ethane-1,2-diimine] dichloridochromium(II) acetonitrile solvate
The title compound, [CrCl2(CH3CN)2(C 26H36N2)]·CH3CN, was synthesized by the reaction of CrCl2(THF)2 with N,N′-bis-(2,6- diisopropyl-phen-yl)ethane-1,2-diimine in dichloro-methane/acetonitrile. The chromium center is coordinated by two N atoms of the chelating diimine ligand, two chloride ions in a trans configuration with respect to each other, and by two N atoms of two acetonitrile mol-ecules in a distorted octa-hedral geometry.
Crystal structure of η5-3,6-di-tert-butyl-4- (tris(pentafluorophenyl)boranyloxycarbonyl)-5-(η5- tetramethylcyclopentadienyl-methyl-9,10,11-trimethyl-bicyclo(6.3.0) undeca-4-en-8,10-dienyl)titanium(III) toluene hemisolvate, Ti(C 51H47BF15O2) · 0.5C 7H8
C54.50H51BF15O2Ti, triclinic, P1̄ (no. 2), a = 11.603(2) Å, b = 12.872(3) Å, c = 18.142(4) Å, α = 76.47(3)°, β = 77.99(3)°, γ = 69.13(3)°, V = 2438.2 Å5, Z = 2, Rgt(F) = 0.048, wRobs(F2) = 0.114, T = 200 K. © by Oldenbourg Wissenchaftsverlag.
Crystal structure of strontium praseodum gallium oxide, SrPrGaO4
GaO4PrSr, tetragonal, I4/mmm (No. 139), a = 3.822(1) Å, c = 12.622(2) Å, V = 184.4 Å3, Z = 2, Rgt(F) = 0.028, wR(F2) = 0.082, T = 293 K.
Crystal structure of rac-[1, 2-ethylene-bis(η5-4, 5, 6, 7-tetrahydroindenyl)]1-hafna-4, 5-bis(trimethylsilyl)furan-3-one- tris(pentafluorophenyl)borane, (C20H24)Hf(Me 3SiC2SiMe3CO2)B(C6F 5)3
C47H42BF15HfO2Si2, monoclinic, P121/n1 (no. 14), a = 15.7496(4) Å = 20.4074(5) Å= 16.3115(5) Å, β = 96.313(2)°, V= 5210.9 Å3, Z = 4, Rgt(F) = 0.027, WRref(F 2) = 0.049, T= 200 K. © by Oldenbourg Wissenschaftsverlag.
Crystal structure of (2,3-bis((2R,5R)-2,5-dimethylphosphonalyl)maleic anhydride)-(η4-norbornadiene)-rhodium(I) tetrafluoroborate, [Rh(C7H8)(C16H24O3P 2)] [BF4]
C23H32BF4O3P2Rh, orthorhombic, P212121 (no. 19), a = 10.147(2) Å, b = 13.246(3) Å, c = 18.827(4) Å, V = 2530.5 Å3, Z = 4, Rgt(F) = 0.025, wRref(F 2) = 0.067, T = 200 K. © by Oldenbourg Wissenschaftsverlag,.
[N,N-Bis(diphenylphosphino)isopropylamine]dibromidonickel(II)
The title compound, [NiBr2(C27H27NP2)], was synthesized by the reaction of NiBr2(dme) (dme is 1,2-dimethoxy-ethane) with N,N-bis-(diphenyl-phosphino)isopropyl-amine in methanol/tetra-hydro-furan. The nickel(II) center is coordinated by two P atoms of the chelating PNP ligand, PH2PN(iPr)PPH2, and two bromide ions in a distorted square-planar geometry.