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- ItemMethyl 5-chloro-2-hydr-oxy-3-(4-methoxyphenyl)-4,6-dimethylbenzoate(Chester : International Union of Crystallography, 2009) Adeel, M.; Ali, I.; Langer, P.; Villinger, A.In the title compound, C17H17ClO4, the dihedral angle between the mean planes of the two benzene rings is 65.92 (5)°. The methyl ester group lies within the ring plane [deviations of O atoms from the plane = -0.051 (2) and 0.151 (2) Å] due to an intra-molecular O - H⋯O hydrogen bond. In the crystal, molecules are held together by rather weak non-classical inter-molecular C - H⋯O hydrogen bonds, resulting in dimeric units about inversion centers, forming eight- and ten-membered ring systems as R22(8) and R2 2(10) motifs. © Adeel et al. 2009.
- Item[1-Dimethylsilyl-2-phenyl-3-(η5-tetramethylcyclopentadienyl) prop-1-en-1-ylκC1](n5-pentamethylcyclopentadienyl)- titanium(III)(Chester : International Union of Crystallography, 2009) Lamač, M.; Spannenberg, A.; Arndt, P.; Rosenthal, U.The title compound, [Ti(C10H15)(C20H 26Si)], was obtained from the reaction of [Ti{5: 1-C5Me4(CH2)}(5-C 5Me5)] with the alkynylsilane PhC2SiMe 2H. The complex crystallizes with two independent mol-ecules in the asymmetric unit, which differ in the conformation of the propenyl unit, resulting in their having opposite helicity. No inter-molecular inter-actions or inter-actions involving the Si- H bond are present. The observed geometrical parameters are unexceptional compared to known structures of the same type.
- Item(μ5-Cyclo-penta-dien-yl)bis-(triphenyl-phosphane)cobalt(I) -toluene-n-hexane (1/0.20/0.25)(Chester : International Union of Crystallography, 2008) Hapke, M.; Spannenberg, A.The title compound, [Co(C5H5)(C18H15P)2]·0.2C7H8·0.25C6H14, was synthesized by the reaction of cobaltocene, Cp2Co, with elemental lithium in tetra-hydro-furan in the presence of two equivalents of PPh3. The mol-ecular structure displays a cobalt(I) center in a distorted trigonal-planar coordination environment, with one Cp and two phosphane ligands. There are two crystallographically independent mol-ecules in the asymmetric unit besides the disordered solvent molecules.
- ItemP-[N-(Diphenyl-phospho-rothio-yl)iso-propyl-amino]-N-isopropyl-P-phenyl- thio-phosphinic amide(Chester : International Union of Crystallography, 2009) Peulecke, N.; Aluri, B.R.; Wöhl, A.; Spannenberg, A.; Al-Hazmi, M.H.The title compound, C24H30N2P2S2, was obtained by the reaction of Ph2PN(iPr)P(Ph)N(iPr)H with elemental sulfur in tetra-hydro-furan. In the solid state, intra-molecular N - H⋯S hydrogen bonding influences the mol-ecular conformation; a P - N - P - N torsion angle of 2.28 (9)° is observed. The two phenyl rings attached to one P atom form a dihedral angle of 74.02 (4)°.
- ItemBis[N,N′-bis-(2,6-diisopropylphenyl)ethane-1,2-diimine] -1κ2 N,N′;2κ2 N,N′-tri - Trichlorido-1:2κ6 Cl:Clchlorido-1Cltetrahydrofuran- 2Odichromium(II) dichloromethane 4.5-solvate(Chester : International Union of Crystallography, 2009) Peitz, S.; Peulecke, N.; Müller, B.H.; Spannenberg, A.; Rosenthal, U.In the mol-ecular structure of the title compound, [Cr2Cl4(C 26H36N2)2(C4H8O)] ·4.5CH2Cl2, the two CrII centers are bridged by three Cl atoms, forming a dinuclear complex. Each CrII center is coordinated by one chelating bis-(2,6-diisopropyl-phen-yl)ethane-1,2-diimine ligand via both N atoms. An additional chloride ion binds to one chromium center, whereas an additional tetra-hydro-furan mol-ecule coordinates to the second CrII center. The coordination geometry at each CrII center can be best described as distorted octa-hedral.
- Item1,1,2,2-Tetra-phenyl-15-diphosphane 1-sulfide(Chester : International Union of Crystallography, 2009) Aluri, B.R.; Peitz, S.; Wöhl, A.; Peulecke, N.; Müller, B.H.; Spannenberg, A.; Rosenthal, U.In the title mol-ecule, C24H20P2S, the P - P bond length is 2.2263 (5) Å. The two phenyl rings attached to the three- and five-coordinated P atoms, respectively, form dihedral angles of 56.22 (5) and 71.74 (5)°.
- ItemDiacetonitrile[N,N′-bis(2,6-diisopropyl-phenyl)ethane-1,2-diimine] dichloridochromium(II) acetonitrile solvate(Chester : International Union of Crystallography, 2009) Peitz, S.; Peulecke, N.; Müller, B.H.; Spannenberg, A.; Rosenthal, U.The title compound, [CrCl2(CH3CN)2(C 26H36N2)]·CH3CN, was synthesized by the reaction of CrCl2(THF)2 with N,N′-bis-(2,6- diisopropyl-phen-yl)ethane-1,2-diimine in dichloro-methane/acetonitrile. The chromium center is coordinated by two N atoms of the chelating diimine ligand, two chloride ions in a trans configuration with respect to each other, and by two N atoms of two acetonitrile mol-ecules in a distorted octa-hedral geometry.
- ItemPyrimidine acyclo-C-nucleosides by ring transformations of 2-formyl-L-arabinal(Basel : MDPI, 2005) Bari, A.; Feist, H.; Michalik, M.; Peseke, K.The protected 2-formyl-L-arabinal 2 reacted with thiourea and cyanamide in the presence of sodium hydride to afford via ring transformations the 5-[1R,2S-1,2-bis(benzyloxy)-3-hydroxypropyl]-1,2-dihydropyrimidines 3 and 4, respectively. Similarly, treatment of 2 with 3-amino-2H-1,2,4-triazole yielded 6-[1R,25-1,2-bis(benzyloxy)-3-hydroxypropyl][1,2,4]-triazolo[1,5-a]pyrimidine(5) .
- ItemAn 8-fold parallel reactor system for combinatorial catalysis research(New York : Hindawi, 2006) Stoll, N.; Allwardt, A.; Dingerdissen, U.; Thurow, K.Increasing economic globalization and mounting time and cost pressure on the development of new raw materials for the chemical industry as well as materials and environmental engineering constantly raise the demands on technologies to be used. Parallelization, miniaturization, and automation are the main concepts involved in increasing the rate of chemical and biological experimentation. Copyright © 2006 Norbert Stoll et al.
- Item[N,N-Bis(diphenylphosphino)isopropylamine]dibromidonickel(II)(Chester : International Union of Crystallography, 2009) Hapke, M.; Wöhl, A.; Peitz, S.; Müller, B.H.; Spannenberg, A.; Rosenthal, U.The title compound, [NiBr2(C27H27NP2)], was synthesized by the reaction of NiBr2(dme) (dme is 1,2-dimethoxy-ethane) with N,N-bis-(diphenyl-phosphino)isopropyl-amine in methanol/tetra-hydro-furan. The nickel(II) center is coordinated by two P atoms of the chelating PNP ligand, PH2PN(iPr)PPH2, and two bromide ions in a distorted square-planar geometry.