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- ItemPolymeric monolithic materials: Syntheses, properties, functionalization and applications(Amsterdam : Elsevier, 2007) Buchmeiser, M.R.The synthetic particularities for the synthesis of polymer-based monolithic materials are summarized. In this context, monoliths prepared via thermal-, UV- or electron-beam triggered free radical polymerization, controlled TEMPO-mediated radical polymerization, polyaddition, polycondensation as well as living ring-opening metathesis polymerization (ROMP) will be covered. Particular attention is devoted to the aspects of controlling pore sizes, pore volumes and pore size distributions as well as functionalization of these supports. Finally, selected, recent applications in separation science, (bio-) catalysis and chip technology will be summarized. © 2007 Elsevier Ltd. All rights reserved.
- ItemInvestigation of changes in crystalline and amorphous structure during deformation of nano-reinforced semi-crystalline polymers by space-resolved synchrotron saxs and waxs(Amsterdam : Elsevier, 2009) Schneider, K.; Schone, A.; Jun, T.-S.; Korsunsky, A.M.Complex structural changes occur in semi-crystalline polymers during deformation. In (nano-)filled systems the situation becomes even more complicated, since not only phase changes may take place, but also local (interfacial) failure between phases may occur. To help identify specific processes taking place within these systems, simultaneous small- and wide-angle X-ray scattering (SAXS/WAXS) measurements were performed using synchrotron radiation during in situ deformation. Using a highly focused beam, spatially resolved local information can be extracted by scanning the beam across the deformed/damaged region within the sample. The characteristic changes in the different phases are presented and discussed. While the study of WAXS patterns gives insight into the orientation and dimensions of the crystallites, SAXS provides information about the mutual arrangement of phases and the interfacial failure phenomena. Based on the analysis of the results obtained in our experiments it will be shown that the first changes in the crystalline phase appear long before macroscopic yielding of the sample is reached, i.e. the onset of irreversible deformation takes place. In the post-yield regime radical changes are observed in both the long- and short-range structures. It is concluded that the presence of nano-fillers exerts a strong influence on the establishment of microcrystalline structure, and hence also on the deformation behaviour at the microscopic scale.
- ItemNew electronic device for driving surface acoustic wave actuators(Amsterdam : Elsevier, 2009) Brünig, R.; Mensel, K.; Kunze, R.; Schmidt, H.Surface acoustic wave (SAW) actuators are driven by a high frequency signal. The frequency range for an ideal SAW-generation is usually very narrow banded and may shift depending on various environmental conditions. We present a new electronic device which self-aligns to the optimal excitation frequency within a wide range. Any kind of SAW-actuator can be used. The device continuously scans a certain frequency range and characterizes the SAW-component. The ideal excitation frequency is then determined and used to drive the SAW-device. In case of changes like loading conditions or temperature variations the device automatically readjusts to the optimal frequency and prevents possible damage of the device or actuator in case of an error. © 2009.
- ItemCCS-Bonds as a superior instrument to incentivize secure carbon sequestration(Amsterdam : Elsevier, 2009) Held, Hermann; Edenhofer, OttmarGeological sequestration of CO2 on a massive scale implies that large area fractions of the underground could become flooded by CO2, imposing a unprecedented regulatory challenge to environmental authorities. Therefore we propose carbon sequestration bonds as complementary, market-based instruments that should further help to manage the risk of decadal-scale CO2 leakage. Such bond schemes address market failures that could occur if the investment behavior of operators under uncertainty differed from society’s preference. For a stylized setup we demonstrate that our bond system has the potential to simultaneously address regulatory challenges stemming from information asymmetries and diverging orders of preference.
- ItemGALS for Bursty Data Transfer based on Clock Coupling(Amsterdam : Elsevier, 2009) Krstić, M.; Fan, X.; Grass, E.; Gürkaynak, F.K.In this paper we introduce a novel burst-mode GALS technique. The goal of this technique is improving the performance of the GALS approach for systems with predominantly bursty data transfer. This new technique has been used to implement a GALS-based version of a hardware accelerator of a 60 GHz OFDM baseband processor. The simulation results show a significant performance improvement in comparison with a classical implementation of GALS using pausible clocking. © 2009 Elsevier B.V. All rights reserved.
- ItemPlanetary geostrophic equations for the atmosphere with evolution of the barotropic flow(Amsterdam : Elsevier, 2009) Dolaptchiev, S.I.; Klein, R.Atmospheric phenomena such as the quasi-stationary Rossby waves, teleconnection patterns, ultralong persistent blockings and the polar/subtropical jet are characterized by planetary spatial scales, i.e. scales of the order of the earth's radius. This motivates our interest in the relevant physical processes acting on the planetary scales. Using an asymptotic approach, we systematically derive reduced model equations valid for atmospheric motions with planetary spatial scales and a temporal scale of the order of about 1 week. We assume variations of the background potential temperature comparable in magnitude with those adopted in the classical quasi-geostrophic theory. At leading order, the resulting equations include the planetary geostrophic balance. In order to apply these equations to the atmosphere, one has to prescribe a closure for the vertically averaged pressure. We present an evolution equation for this component of the pressure which was derived in a systematic way from the asymptotic analysis. Relative to the prognostic closures adopted in existing reduced-complexity planetary models, this new dynamical closure may provide for more realistic increased large-scale, long-time variability in future implementations. © 2008 Elsevier B.V. All rights reserved.
- ItemLow-stabilisation scenarios and technologies for carbon capture and sequestration(Amsterdam : Elsevier, 2009) Bauer, N.; Edenhofer, O.; Leimbach, M.Endogenous technology scenarios for meeting low stabilization CO2 targets are derived in this study and assessed regarding emission reductions and mitigation costs. The aim is to indentify the most important technology options for achieving low stabilization targets. The significance of an option is indicated by its achieved emission reduction and the mitigation cost increase, if this option were not available. Quantitative results are computed using a global multi-regional hard-linked hybrid model that integrates the economy, the energy sector and the climate system. The model endogenously determines the optimal deployment of technologies subject to a constraint on climate change. The alternative options in the energy sector comprise the most important mitigation technologies: renewables, biomass, nuclear, carbon capture and sequestration (CCS), and biomass with CCS as well as energy efficiency improvements. The results indicate that the availability of CCS technologies and espec. biomass with CCS is highly desirable for achieving low stabilization goals at low costs. The option of nuclear energy is different: although it could play an important role in the primary energy mix, mitigation costs would only mildly increase, if it could not be expanded. Therefore, in order to promote prudent climate change mitigation goals, support of CCS technologies reduces the costs and-thus-is desirable from a social point of view. © 2009 Elsevier Ltd. All rights reserved.
- ItemUltimate response dynamics achieved with gas sensors based on self-heated nanowires(Amsterdam : Elsevier, 2009) Prades, J.D.; Jimenez-Diaz, R.; Hernandez-Ramirez, F.; Romano-Rodriguez, A.; Mathur, S.; Morante, J.R.Bias current applied to conductometric gas sensors consisting of individual metal oxide nanowires can be used to heat them up to the temperature necessary for sensing. This approach in combination with the good sensitivity and stability of metal-oxide nanowires, can be used to develop prototypes with low power requirements (few tens of microwatts). Here, we present new sensors devices based on this approach that display fast dynamic performance only limited by the gas-solid interaction kinetics,. © 2009.
- ItemModification of Newton's law of gravity at very large distances(Amsterdam : Elsevier, 2002) Kirillov, A.A.; Turaev, D.We discuss a Modified Field Theory (MOFT) in which the number of fields can vary. It is shown that when the number of fields is conserved MOFT reduces to the standard field theory but interaction constants undergo an additional renormalization and acquire a dependence on spatial scales. In particular, the renormalization of the gravitational constant leads to the deviation of the law of gravity from the Newton's law in some range of scales rmin < r < rmax, in which the gravitational potential shows essentially logarithmic ∼ ln r (instead of 1/r) behavior. In this range, the renormalized value of the gravitational constant G increases and at scales r > rmax acquires a new constant value G′ ∼ Grmax/rmin. From the dynamical standpoint this looks as if every point source is surrounded with a halo of dark matter. It is also shown that if the maximal scale rmax is absent, the homogeneity of the dark matter in the Universe is consistent with a fractal distribution of baryons in space, in which the luminous matter is located on thin two-dimensional surfaces separated by empty regions of ever growing size.