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End date: 2019 × DDC: 540 × Publisher: Cambridge : Soc. × Subject: chemical structure × WGL Institute: LIKAT ×

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Now showing 1 - 2 of 2
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    A neutral low-coordinate heterocyclic bismuth-tin species
    (Cambridge : Soc., 2015) Hering-Junghans, C.; Schulz, A.; Villinger, A.
    The reaction of distannadiazane bearing bulky RAr*-groups (RAr* = C6H2{C(H)Ph2}2R-2,6,4; R = iPr, tBu) with ECl3 (E = Sb, Bi) was studied resulting in the isolation of previously unknown N,N-bis(dichloropnictino)amines (3) and a novel heterocyclic carbenoid bismuth species (4) bearing a Bi(III) and a Sn(IV) center. The structure and bonding was investigated by means of X-ray structure elucidations and DFT calculations.
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    Accessing heavy allyl-analogous [(TerN)2E]− (E = Sb, Bi) ions and their reactivity towards ECl3
    (Cambridge : Soc., 2015) Hinz, Alexander; Schulz, Axel; Villinger, Alexander
    The attempted preparation of the biradicaloid [E(μ-NTer)]2 (E = Sb, Bi) yielded salts of the anion [(TerN)2E]−. These heteroatom allyl analogues could be further utilized in the reaction with pnictogen(III) chlorides to form the first 1,3-dichloro-1-bisma-3-stiba-2,4-diazane [ClSb(μ-NTer)2BiCl].