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- ItemDesigning Hierarchical ZSM-5 Materials for Improved Production of LPG Olefins in the Catalytic Cracking of Triglycerides(New York, NY : Hindawi, 2019) Vu, Xuan Hoan; Armbruster, UdoLPG olefins (propene and butenes) are key building blocks in the petrochemical industry whose demand has been expanding steadily in recent years. The use of FCC (fluid catalytic cracking) units for conversion of triglycerides is a promising option for the future to boost production of LPG olefins. However, a need for innovative cracking catalysts is rising due to the different nature between petroleum and biomass-derived feedstocks. In this study, series of hierarchical ZSM-5 materials, namely, mesoporous ZSM-5, nanosized ZSM-5, and composite ZSM-5 were prepared, aiming to enhance the production of LPG olefins along with transportation fuels. Mesoporous ZSM-5 materials were synthesized by the postsynthetic modifications involving base treatment and subsequent acid washing, whereas nanosized ZSM-5 and composite ZSM-5 were synthesized by the direct-synthetic routes for a comparative purpose. The obtained materials were characterized by XRD, FTIR, N2 sorption, TEM, AAS, ICP-AES, and NH3-TPD, and their catalytic performance was assessed in the cracking of triolein as a representative of triglycerides under FCC conditions. It was found that the subsequent strong acid washing step of alkaline treated ZSM-5 for removal of aluminum debris and external acid sites is needed to improve the catalytic performance. The resulting mesoporous ZSM-5 material shows higher yields of the desired products, i.e., gasoline and LPG olefins than its parent, commercial ZSM-5 at the almost complete conversion (ca. 90 wt.%). The selectivity toward LPG olefins is also enhanced over all the hierarchical ZSM-5 materials, particularly high for composite ZSM-5 (ca. 94 wt.%). The improved diffusion and lowered acidity of the hierarchical ZSM-5 materials might be responsible for their superior catalytic performance. © 2019 Xuan Hoan Vu and Udo Armbruster.
- ItemModelling the Dependency between Inflation and Exchange Rate Using Copula(New York, NY : Hindawi, 2020) Kwofie, Charles; Akoto, Isaac; Opoku-Ameyaw, KwakuIn this paper, we propose a copula approach in measuring the dependency between inflation and exchange rate. In unveiling this dependency, we first estimated the best GARCH model for the two variables. Then, we derived the marginal distributions of the standardised residuals from the GARCH. The Laplace and generalised t distributions best modelled the residuals of the GARCH(1,1) models, respectively, for inflation and exchange rate. These marginals were then used to transform the standardised residuals into uniform random variables on a unit interval [0, 1] for estimating the copulas. Our results show that the dependency between inflation and exchange rate in Ghana is approximately 7%.
- ItemZero-Offset VSP Monitoring of CO2Storage: Impedance Inversion and Wedge Modelling at the Ketzin Pilot Site(New York, NY : Hindawi, 2014) Götz, Julia; Lüth, Stefan; Krawczyk, Charlotte M.; Cosma, CalinAt the CO2 storage pilot site near the town of Ketzin (35 km west of Berlin, Germany) the sandstone reservoir at 630 m–650 m depth is thin and heterogeneous. The time-lapse analysis of zero-offset VSP measurements shows that CO2-induced amplitude changes can be observed on near-well corridor stacks. Further, we investigate whether CO2-induced amplitude changes in the monitoring data can be used to derive geometrical and petrophysical parameters governing the migration of CO2 within a brine saturated sandstone aquifer. 2D seismic-elastic modelling is done to test the processing workflow and to perform a wedge modelling study for estimation of the vertical expansion of the CO2 plume. When using the NRMS error as a measure for the similarity between the modelled and recorded repeat traces, the best match is achieved for a plume thickness of 6-7 m within the reservoir sandstone of 8 m thickness. With band limited impedance inversion a velocity reduction at the top of the reservoir of 30%, influenced by casing reverberations as well as CO2 injection, is found. The relation of seismic amplitude to CO2 saturated layer thickness and CO2-induced changes in P-wave velocities are important parameters for the quantification of the injected CO2 volume.
- ItemFunctional Polymeric Materials Based on Cellulose(New York, NY : Hindawi, 2016) Qi, Haisong; Lu, Ang; Zheng, Qingbin; Yang, Quanling[No abstract available]
- ItemDifferential influence of components resulting from atmospheric-pressure plasma on integrin expression of human HaCaT keratinocytes(New York, NY : Hindawi, 2013) Haertel, B.; Straßenburg, S.; Oehmigen, K.; Wende, K.; Von Woedtke, T.; Lindequist, U.Adequate chronic wound healing is a major problem in medicine. A new solution might be non-thermal atmospheric-pressure plasma effectively inactivating microorganisms and influencing cells in wound healing. Plasma components as, for example, radicals can affect cells differently. HaCaT keratinocytes were treated with Dielectric Barrier Discharge plasma (DBD/air, DBD/argon), ozone or hydrogen peroxide to find the components responsible for changes in integrin expression, intracellular ROS formation or apoptosis induction. Dependent on plasma treatment time reduction of recovered cells was observed with no increase of apoptotic cells, but breakdown of mitochondrial membrane potential. DBD/air plasma increased integrins and intracellular ROS. DBD/argon caused minor changes. About 100 ppm ozone did not influence integrins. Hydrogen peroxide caused similar effects compared to DBD/air plasma. In conclusion, effects depended on working gas and exposure time to plasma. Short treatment cycles did neither change integrins nor induce apoptosis or ROS. Longer treatments changed integrins as important for influencing wound healing. Plasma effects on integrins are rather attributed to induction of other ROS than to generation of ozone. Changes of integrins by plasma may provide new solutions of improving wound healing, however, conditions are needed which allow initiating the relevant influence on integrins without being cytotoxic to cells.
- ItemGrowth induction and low-oxygen apoptosis inhibition of human CD34 + progenitors in collagen gels(New York, NY : Hindawi, 2013) Avitabile, D.; Salchert, K.; Werner, C.; Capogrossi, M.C.; Pesce, M.Various reports have indicated low survival of injected progenitors into unfavorable environments such as the ischemic myocardium or lower limb tissues. This represents a major bottleneck in stem-cell-based cardiovascular regenerative medicine. Strategies to enhance survival of these cells in recipient tissues have been therefore sought to improve stem cell survival and ensure long-term engraftment. In the present contribution, we show that embedding human cord blood-derived CD34+ cells into a collagen I-based hydrogel containing cytokines is a suitable strategy to promote stem cell proliferation and protect these cells from anoxia-induced apoptosis.