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Deckert V.
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Deckert-Gaudig T.
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Singh P.
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Zhang Z.
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Bond formation
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2-mercaptopyridine
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Deprotonation
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Surface plasmons
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Tip-enhanced Raman scatterings
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2020
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Cambridge : Royal Society of Chemistry
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Plasmon induced deprotonation of 2-mercaptopyridine
(
Cambridge : Royal Society of Chemistry,
2020
)
Singh P.
;
Deckert-Gaudig T.
;
Zhang Z.
;
Deckert V.
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Surface plasmons can provide a novel route to induce and simultaneously monitor selective bond formation and breakage. Here pH-induced protonation, followed by plasmon-induced deprotonation of 2-mercaptopyridine was investigated using surface- and tip-enhanced Raman scattering (SERS and TERS). A large difference in the deprotonation rate between SERS and TERS will be demonstrated and discussed with respect to hot-spot distribution. © 2020 The Royal Society of Chemistry.
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