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- ItemHigh-Resolution Inkjet Printing of Quantum Dot Light-Emitting Microdiode Arrays(Weinheim : Wiley-VCH Verlag, 2020) Yang, P.; Zhang, L.; Kang, D.J.; Strahl, R.; Kraus, T.The direct printing of microscale quantum dot light-emitting diodes (QLEDs) is a cost-effective alternative to the placement of pre-formed LEDs. The quality of printed QLEDs currently is limited by nonuniformities in droplet formation, wetting, and drying during inkjet printing. Here, optimal ink formulation which can suppress nonuniformities at the pixel and array levels is demonstrated. A solvent mixture is used to tune the ejected droplet size, ensure wetting, and provoke Marangoni flows that prevent coffee stain rings. Arrays of green QLED devices are printed at a resolution of 500 pixels in.−1 with a maximum luminance of ≈3000 cd m−2 and a peak current efficiency of 2.8 cd A−1. The resulting array quality is sufficient to print displays at state-of-the-art resolutions.
- ItemTopographical anisotropy and wetting of ground stainless steel surfaces(Basel : MDPI AG, 2012) Calvimontes, A.; Mauermann, M.; Bellmann, C.Microscopic and physico-chemical methods were used for a comprehensive surface characterization of different mechanically modified stainless steel surfaces. The surfaces were analyzed using high-resolution confocal microscopy, resulting in detailed information about the topographic properties. In addition, static water contact angle measurements were carried out to characterize the surface heterogeneity of the samples. The effect of morphological anisotropy on water contact angle anisotropy was investigated. The correlation between topography and wetting was studied by means of a model of wetting proposed in the present work, that allows quantifying the air volume of the interface water drop-stainless steel surface.
- ItemOn the co-alignment of solar telescopes. A new approach to solar pointing(Milton Park : Taylor & Francis, 2013) Staiger, J.Helioseismological measurements require long observing times and thus may be adversely affected by lateral image drifts as caused by pointing instabilities. At the Vacuum Tower Telescope VTT, Tenerife we have recorded drift values of up to 5" per hour under unstable thermal conditions (dome opening, strong day-to-day thermal gradients). Typically drifts of 0.5" – 1.0" per hour may be encountered under more favorable conditions. Past experience has shown that most high-resolution solar telescopes may be affected by this problem to some degree. This inherent shortcoming of solar pointing is caused by the fact that the guiding loop can be closed only within the guiding beam but not within the telescope's main beam. We have developed a new approach to this problem. We correlate continuum brightness patterns observed from within the telescope main beam with patterns originating from a full disk telescope. We show that brightness patterns of sufficient size are unique with respect to solar location at any instant of time and may serve as a location identifier. We make use of the fact that averaged location information of solar structures is invariant with respect to telescope resolution. We have carried out tests at the VTT together with SDO. We have used SDO as a full disk reference. We were able to reduce lateral image drifts by an order of magnitude.
- ItemGeneral Time-Dependent Configuration-Interaction Singles II: The Atomic Case(Woodbury, NY : Inst., 2022-10-10) Carlström, Stefanos; Bertolino, Mattias; Dahlström, Jan Marcus; Patchkovskii, SergueiWe present a specialization of the grid-based implementation of the time-dependent configuration-interaction singles described in the preceding paper [S. Carlström et al., preceding paper, Phys. Rev. A 106, 043104 (2022)]. to the case of spherical symmetry. We describe the intricate time propagator in detail and conclude with a few example calculations. Among these, of note are high-resolution photoelectron spectra in the vicinity of the Fano resonances in photoionization of neon and spin-polarized photoelectrons from xenon, in agreement with recent experiments.
- ItemNanoplasmonic electron acceleration in silver clusters studied by angular-resolved electron spectroscopy(Bristol : IOP, 2012) Passig, J.; Irsig, R.; Truong, N.X.; Fennel, T.; Tiggesbäumker, J.; Meiwes-Broer, K.H.The nanoplasmonic field enhancement effects in the energetic electron emission from few-nm-sized silver clusters exposed to intense femtosecond dual pulses are investigated by high-resolution double differential electron spectroscopy. For moderate laser intensities of 10 14Wcm -2, the delaydependent and angular-resolved electron spectra show laser-aligned emission of electrons up to keV kinetic energies, exceeding the ponderomotive potential by two orders of magnitude. The importance of the nanoplasmonic field enhancement due to resonant Mie-plasmon excitation observed for optimal pulse delays is investigated by a direct comparison with molecular dynamics results. The excellent agreement of the key signatures in the delay-dependent and angular-resolved spectra with simulation results allows for a quantitative analysis of the laser and plasmonic contributions to the acceleration process. The extracted field enhancement at resonance verifies the dominance of surfaceplasmon-assisted re-scattering.
- ItemEnergy and symmetry of dd excitations in undoped layered cuprates measured By Cu L3 resonant inelastic x-ray scattering(Bristol : IOP, 2011) Moretti Sala, M.; Bisogni, V.; Aruta, C.; Balestrino, G.; Berger, H.; Brookes, N.B.; De Luca, G.M.; Di Castro, D.; Grioni, M.; Guarise, M.; Medaglia, P.G.; Miletto, Granozio, F.; Minola, M.; Perna, P.; Radovic, M.; Salluzzo, M.; Schmitt, T.; Zhou, K.J.; Braicovich, L.; Ghiringhelli, G.We measured the high-resolution Cu L3 edge resonant inelastic x-ray scattering (RIXS) of undoped cuprates La2CuO4, Sr2CuO2Cl2, CaCuO2 and NdBa 2Cu3O6. The dominant spectral features were assigned to dd excitations and we extensively studied their polarization and scattering geometry dependence. In a pure ionic picture, we calculated the theoretical cross sections for those excitations and used these to fit the experimental data with excellent agreement. By doing so, we were able to determine the energy and symmetry of Cu-3d states for the four systems with unprecedented accuracy and confidence. The values of the effective parameters could be obtained for the singleion crystal field model but not for a simple two-dimensional cluster model. The firm experimental assessment of dd excitation energies carries important consequences for the physics of high-Tc superconductors. On the one hand, we found that the minimum energy of orbital excitation is always ≥ 1.4 eV, i.e. well above the mid-infrared spectral range, which leaves to magnetic excitations (up to 300 meV) a major role in Cooper pairing in cuprates. On the other hand, it has become possible to study quantitatively the effective influence of dd excitations on the superconducting gap in cuprates.
- ItemOn the efficiency of bile salt for stable suspension and isolation of single-walled carbon nanotubes-spectroscopic and microscopic investigations(Berlin : Springer Verlag, 2010) Lukaszczuk, P.; Borowiak-Palen, E.; Rümmeli, M.H.; Kalenczuk, R.J.In this contribution we present a systematic study on the dispersion of SWCNTs in a water-based solution of biocompatible detergent: sodium deoxycholate (DOC). By avoiding harsh chemical conditions, which are known to damage nanotubes structure, a stable SWCNTs suspension was created. Long term stirring of the solution led to preparation of a stable transparent solution, containing welldispersed isolated SWCNTs. The as-prepared dispersion remained stable and clear for two months. Optical absorption spectroscopy was employed to measure SWCNTs suspension stability. Nanotube aggregation was evaluated through the tangential mode (G mode) present in the Raman spectrum. High-resolution transmission electronmicroscopy was employed to observe the mechanism of debundling process. © 2010 Springer-Verlag.
- ItemThree-dimensional monitoring of soil water content in a maize field using Electrical Resistivity Tomography(Munich : EGU, 2013) Beff, L.; Günther, T.; Vandoorne, B.; Couvreur, V.; Javaux, M.A good understanding of the soil water content (SWC) distribution at the field scale is essential to improve the management of water, soil and crops. Recent studies proved that Electrical Resistivity Tomography (ERT) opens interesting perspectives in the determination of the SWC distribution in 3 dimensions (3-D). This study was conducted (i) to check and validate how ERT is able to monitor SWC distribution in a maize field during the late growing season; and (ii) to investigate how maize plants and rainfall affect the dynamics of SWC distribution. Time Domain Reflectometry (TDR) measurements were used to validate ERT-inverted SWC values. Evolution of water mass balance was also calculated to check whether ERT was capable of giving a reliable estimate of soil water stock evolution. It is observed that ERT was able to give the same average SWC as TDR (R2 = 0.98). In addition, ERT gives better estimates of the water stock than TDR thanks to its higher spatial resolution. The high resolution of ERT measurements also allows for the discrimination of SWC heterogeneities. The SWC distribution showed that alternation of maize rows and inter-rows was the main influencing factor of the SWC distribution. The drying patterns were linked to the root profiles, with drier zones under the maize rows. During short periods, with negligible rainfall, the SWC decrease took place mainly in the two upper soil horizons and in the inter-row area. In contrast, rainfall increased the SWC mostly under the maize rows and in the upper soil layer. Nevertheless, the total amount of rainfall during the growing season was not sufficient to modify the SWC patterns induced by the maize rows. During the experimental time, there was hardly any SWC redistribution from maize rows to inter-rows. Yet, lateral redistribution from inter-rows to maize rows induced by potential gradient generates SWC decrease in the inter-row area and in the deeper soil horizons.
- ItemReport on ICDP Deep Dust workshops: probing continental climate of the late Paleozoic icehouse–greenhouse transition and beyond(Sapporo : IODP, 2020) Soreghan, Gerilyn S.; Beccaletto, Laurent; Benison, Kathleen C.; Bourquin, Sylvie; Feulner, Georg; Hamamura, Natsuko; Hamilton, Michael; Heavens, Nicholas G.; Hinnov, Linda; Huttenlocker, Adam; Looy, Cindy; Pfeifer, Lily S.; Pochat, Stephane; Sardar Abadi, Mehrdad; Zambito, JamesChamberlin and Salisbury's assessment of the Permian a century ago captured the essence of the period: it is an interval of extremes yet one sufficiently recent to have affected a biosphere with near-modern complexity. The events of the Permian - the orogenic episodes, massive biospheric turnovers, both icehouse and greenhouse antitheses, and Mars-analog lithofacies - boggle the imagination and present us with great opportunities to explore Earth system behavior. The ICDP-funded workshops dubbed "Deep Dust," held in Oklahoma (USA) in March 2019 (67 participants from nine countries) and Paris (France) in January 2020 (33 participants from eight countries), focused on clarifying the scientific drivers and key sites for coring continuous sections of Permian continental (loess, lacustrine, and associated) strata that preserve high-resolution records. Combined, the two workshops hosted a total of 91 participants representing 14 countries, with broad expertise. Discussions at Deep Dust 1.0 (USA) focused on the primary research questions of paleoclimate, paleoenvironments, and paleoecology of icehouse collapse and the run-up to the Great Dying and both the modern and Permian deep microbial biosphere. Auxiliary science topics included tectonics, induced seismicity, geothermal energy, and planetary science. Deep Dust 1.0 also addressed site selection as well as scientific approaches, logistical challenges, and broader impacts and included a mid-workshop field trip to view the Permian of Oklahoma. Deep Dust 2.0 focused specifically on honing the European target. The Anadarko Basin (Oklahoma) and Paris Basin (France) represent the most promising initial targets to capture complete or near-complete stratigraphic coverage through continental successions that serve as reference points for western and eastern equatorial Pangaea. © 2020 Copernicus GmbH. All rights reserved.
- ItemRemote Sensing Based Yield Estimation of Rice (Oryza Sativa L.) Using Gradient Boosted Regression in India(Basel : MDPI, 2021) Arumugam, Ponraj; Chemura, Abel; Schauberger, Bernhard; Gornott, ChristophAccurate and spatially explicit yield information is required to ensure farmers’ income and food security at local and national levels. Current approaches based on crop cutting experiments are expensive and usually too late for timely income stabilization measures like crop insurances. We, therefore, utilized a Gradient Boosted Regression (GBR), a machine learning technique, to estimate rice yields at ~500 m spatial resolution for rice-producing areas in India with potential application for near real-time estimates. We used resampled intermediate resolution (~5 km) images of the Moderate Resolution Imaging Spectroradiometer (MODIS) Leaf Area Index (LAI) and observed yields at the district level in India for calibrating GBR models. These GBRs were then used to downscale district yields to 500 m resolution. Downscaled yields were re-aggregated for validation against out-of-sample district yields not used for model training and an additional independent data set of block-level (below district-level) yields. Our downscaled and re-aggregated yields agree well with reported district-level observations from 2003 to 2015 (r = 0.85 & MAE = 0.15 t/ha). The model performance improved further when estimating separate models for different rice cropping densities (up to r = 0.93). An additional out-of-sample validation for the years 2016 and 2017, proved successful with r = 0.84 and r = 0.77, respectively. Simulated yield accuracy was higher in water-limited, rainfed agricultural systems. We conclude that this downscaling approach of rice yield estimation using GBR is feasible across India and may complement current approaches for timely rice yield estimation required by insurance companies and government agencies.