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    Coherent control of electron spin qubits in silicon using a global field
    (London : Nature Publ. Group, 2022) Vahapoglu, E.; Slack-Smith, J.P.; Leon, R.C.C.; Lim, W.H.; Hudson, F.E.; Day, T.; Cifuentes, J.D.; Tanttu, T.; Yang, C. H.; Saraiva, A.; Abrosimov, N.V.; Pohl, H.J.; Thewalt, M.L.W.; Laucht, A.; Dzurak, A.S.; Pla, J.J.
    Silicon spin qubits promise to leverage the extraordinary progress in silicon nanoelectronic device fabrication over the past half century to deliver large-scale quantum processors. Despite the scalability advantage of using silicon technology, realising a quantum computer with the millions of qubits required to run some of the most demanding quantum algorithms poses several outstanding challenges, including how to control many qubits simultaneously. Recently, compact 3D microwave dielectric resonators were proposed as a way to deliver the magnetic fields for spin qubit control across an entire quantum chip using only a single microwave source. Although spin resonance of individual electrons in the globally applied microwave field was demonstrated, the spins were controlled incoherently. Here we report coherent Rabi oscillations of single electron spin qubits in a planar SiMOS quantum dot device using a global magnetic field generated off-chip. The observation of coherent qubit control driven by a dielectric resonator establishes a credible pathway to achieving large-scale control in a spin-based quantum computer.
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    De novo rational design of a freestanding, supercharged polypeptide, proton-conducting membrane
    (Washington : American Association for the Advancement of Science (A A A S), 2020) Ma, Chao; Dong, Jingjin; Viviani, Marco; Tulini, Isotta; Pontillo, Nicola; Maity, Sourav; Zhou, Yu; Roos, Wouter H.; Liu, Kai; Herrmann, Andreas; Portale, Giuseppe
    Proton translocation enables important processes in nature and man-made technologies. However, controlling proton conduction and fabrication of devices exploiting biomaterials remains a challenge. Even more difficult is the design of protein-based bulk materials without any functional starting scaffold for further optimization. Here, we show the rational design of proton-conducting, protein materials exceeding reported proteinaceous systems. The carboxylic acid-rich structures were evolved step by step by exploring various sequences from intrinsically disordered coils over supercharged nanobarrels to hierarchically spider β sheet containing protein-supercharged polypeptide chimeras. The latter material is characterized by interconnected β sheet nanodomains decorated on their surface by carboxylic acid groups, forming self-supportive membranes and allowing for proton conduction in the hydrated state. The membranes showed an extraordinary proton conductivity of 18.5 ± 5 mS/cm at RH = 90%, one magnitude higher than other protein devices. This design paradigm offers great potential for bioprotonic device fabrication interfacing artificial and biological systems. Copyright © 2020 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution NonCommercial License 4.0 (CC BY-NC).