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- ItemGlycerylphytate as an ionic crosslinker for 3D printing of multi-layered scaffolds with improved shape fidelity and biological features(London : Royal Society of Chemistry, 2020) Mora-Boza, A.; Włodarczyk-Biegun, M.K.; Del Campo, A.; Vázquez-Lasa, B.; Román, J.S.The fabrication of intricate and long-term stable 3D polymeric scaffolds by a 3D printing technique is still a challenge. In the biomedical field, hydrogel materials are very frequently used because of their excellent biocompatibility and biodegradability, however the improvement of their processability and mechanical properties is still required. This paper reports the fabrication of dual crosslinked 3D scaffolds using a low concentrated (<10 wt%) ink of gelatin methacryloyl (GelMA)/chitosan and a novel crosslinking agent, glycerylphytate (G1Phy) to overcome the current limitations in the 3D printing field using hydrogels. The applied methodology consisted of a first ultraviolet light (UV) photopolymerization followed by a post-printing ionic crosslinking treatment with G1Phy. This crosslinker provides a robust framework and avoids the necessity of neutralization with strong bases. The blend ink showed shear-thinning behavior and excellent printability in the form of a straight and homogeneous filament. UV curing was undertaken simultaneously to 3D deposition, which enhanced precision and shape fidelity (resolution ≈150 μm), and prevented the collapse of the subsequent printed layers (up to 28 layers). In the second step, the novel G1Phy ionic crosslinker agent provided swelling and long term stability properties to the 3D scaffolds. The multi-layered printed scaffolds were mechanically stable under physiological conditions for at least one month. Preliminary in vitro assays using L929 fibroblasts showed very promising results in terms of adhesion, spreading, and proliferation in comparison to other phosphate-based traditional crosslinkers (i.e. TPP). We envision that the proposed combination of the blend ink and 3D printing approach can have widespread applications in the regeneration of soft tissues.
- ItemEffects of substitution pattern in phosphite ligands used in rhodium-catalyzed hydroformylation on reactivity and hydrolysis stability(Basel : MDPI, 2019) Kloß, Svenja; Selent, Detlef; Spannenberg, Anke; Franke, Robert; Börner, Armin; Sharif, MuhammadThe stability of homogeneous catalytic systems is an industrially crucial topic, which, however, receives comparatively little attention from academic research. Phosphites are among the most frequently used ligands in industrial, rhodium-catalyzed n-regioselective hydroformylation. However, they are particularly vulnerable to hydrolysis. Since the decomposition of ligands should be dependent on the substitution patterns, phenyl, tert-butyl and condensed ring systems of benzopinacolphosphites were evaluated concerning their activity, regioselectivity and hydrolysis stability. A series of twelve strongly related phosphites were synthesized, tested in the hydroformylation of isomeric n-octenes, and studied in hydrolysis experiments using in situ NMR spectroscopy. Our results show that substituents in the ortho-position, especially tert-butyl substituents, enhance hydrolysis stability while maintaining compelling activity and regioselectivity. In contrast, substituents in the para-position may destabilize the phosphite. © 2019 by the authors. Licensee MDPI, Basel, Switzerland.
- ItemHigh temperature behavior of rual thin films on piezoelectric CTGS and LGS substrates(Basel : MDPI AG, 2020) Seifert, M.This paper reports on a significant further improvement of the high temperature stability of RuAl thin films (110 nm) on the piezoelectric Ca3TaGa3Si2O14 (CTGS) and La3Ga5SiO14 (LGS) substrates. RuAl thin films with AlN or SiO2 cover layers and barriers to the substrate (each 20 nm), as well as a combination of both were prepared on thermally oxidized Si substrates, which serve as a reference for fundamental studies, and the piezoelectric CTGS, as well as LGS substrates. In somefilms, additional Al layers were added. To study their high temperature stability, the samples were annealed in air and in high vacuum up to 900 °C, and subsequently their cross-sections, phase formation, film chemistry, and electrical resistivity were analyzed. It was shown that on thermally oxidized Si substrates, all films were stable after annealing in air up to 800 °C and in high vacuum up to 900 °C. The high temperature stability of RuAl thin films on CTGS substrates was improved up to 900 °C in high vacuum by the application of a combined AlN/SiO2 barrier layer and up to 800 °C in air using a SiO2 barrier. On LGS, the films were only stable up to 600 °C in air; however, a single SiO2 barrier layer was sufficient to prevent oxidation during annealing at 900 °C in high vacuum.
- ItemObservation of discrete, vortex light bullets(College Park : American Institute of Physics Inc., 2014) Eilenberger, F.; Prater, K.; Minardi, S.; Geiss, R.; Röpke, U.; Kobelke, J.; Schuster, K.; Bartelt, H.; Nolte, S.; Tünnermann, A.; Pertsch, T.We report the first experimental observation of vortex light bullets that are discrete, spatiotemporal, solitary waves with orbital angular momentum. We analyze conditions for their existence and investigate their rich properties and dynamics. Vortex light bullets are excited in fiber arrays with spatially shaped femtosecond pulses and analyzed with a spatiotemporal cross correlator. Most importantly, we find that they have entirely new stability properties, being robust against considerable degrees of perturbation in a limited range of energies. All experimental findings are backed up by rigorous simulations, giving further insight into the rich dynamics of vortex light bullets.
- ItemThe invariant distribution of wealth and employment status in a small open economy with precautionary savings(Amsterdam : North-Holland, 2019) Bayer, Christian; Rendall, Alan D.; Wälde, KlausWe study optimal savings in continuous time with exogenous transitions between employment and unemployment as the only source of uncertainty in a small open economy. We prove the existence of an optimal consumption path. We exploit that the dynamics of consumption and wealth between jumps can be expressed as a Fuchsian system. We derive conditions under which an invariant joint distribution for the state variables, i.e., wealth and labour market status, exists and is unique. We also provide conditions under which the distribution of these variables converges to the invariant distribution. Our analysis relies on the notion of T-processes and applies results on the stability of Markovian processes from Meyn and Tweedie (1993a, b,c). © 2019 The Author(s)
- ItemToward Reliable Multi-Level Operation in RRAM Arrays: Improving Post-Algorithm Stability and Assessing Endurance/Data Retention(Piscataway : Institute of Electrical and Electronics Engineers Inc., 2019) Perez, E.; Zambelli, C.; Mahadevaiah, M.K.; Olivo, P.; Wenger, C.Achieving a reliable multi-level operation in resistive random access memory (RRAM) arrays is currently a challenging task due to several threats like the post-algorithm instability occurring after the levels placement, the limited endurance, and the poor data retention capabilities at high temperature. In this paper, we introduced a multi-level variation of the state-of-the-art incremental step pulse with verify algorithm (M-ISPVA) to improve the stability of the low resistive state levels. This algorithm introduces for the first time the proper combination of current compliance control and program/verify paradigms. The validation of the algorithm for forming and set operations has been performed on 4-kbit RRAM arrays. In addition, we assessed the endurance and the high temperature multi-level retention capabilities after the algorithm application proving a 1 k switching cycles stability and a ten years retention target with temperatures below 100 °C.
- ItemHow Price-Based Frequency Regulation Impacts Stability in Power Grids: A Complex Network Perspective(London : Hindawi, 2020) Ji, Peng; Zhu, Lipeng; Lu, Chao; Lin, Wei; Kurths, JürgenWith the deregulation of modern power grids, electricity markets are playing a more and more important role in power grid operation and control. However, it is still questionable how the real-time electricity price-based operation affects power grid stability. From a complex network perspective, here we investigate the dynamical interactions between price-based frequency regulations and physical networks, which results in an interesting finding that a local minimum of network stability occurs when the response strength of generators/consumers to the varying price increases. A case study of the real world-based China Southern Power Grid demonstrates the finding and exhibits a feasible approach to network stability enhancement in smart grids. This also provides guidance for potential upgrade and expansion of the current power grids in a cleaner and safer way. © 2020 Peng Ji et al.
- ItemAnalysis of a bistable climate toy model with physics-based machine learning methods(Berlin ; Heidelberg : Springer, 2021) Gelbrecht, Maximilian; Lucarini, Valerio; Boers, Niklas; Kurths, JürgenWe propose a comprehensive framework able to address both the predictability of the first and of the second kind for high-dimensional chaotic models. For this purpose, we analyse the properties of a newly introduced multistable climate toy model constructed by coupling the Lorenz ’96 model with a zero-dimensional energy balance model. First, the attractors of the system are identified with Monte Carlo Basin Bifurcation Analysis. Additionally, we are able to detect the Melancholia state separating the two attractors. Then, Neural Ordinary Differential Equations are applied to predict the future state of the system in both of the identified attractors.
- ItemStability of Weak Solutions to Parabolic Problems with Nonstandard Growth and Cross–Diffusion(Basel : MDPI, 2021) Erhardt, André H.We study the stability of a unique weak solution to certain parabolic systems with nonstandard growth condition, which are additionally dependent on a cross-diffusion term. More precisely, we show that two unique weak solutions of the considered system with different initial values are controlled by their initial values.
- ItemImproving power grid transient stability by plug-in electric vehicles(Bristol : Institute of Physics Publishing, 2014) Gajduk, A.; Todorovski, M.; Kurths, J.; Kocarev, L.Plug-in electric vehicles (PEVs) can serve in discharge mode as distributed energy and power resources operating as vehicle-to-grid (V2G) devices and in charge mode as loads or grid-to-vehicle devices. It has been documented that PEVs serving as V2G systems can offer possible backup for renewable power sources, can provide reactive power support, active power regulation, load balancing, peak load shaving, can reduce utility operating costs and can generate revenue. Here we show that PEVs can even improve power grid transient stability, that is, stability when the power grid is subjected to large disturbances, including bus faults, generator and branch tripping, and sudden large load changes. A control strategy that regulates the power output of a fleet of PEVs based on the speed of generator turbines is proposed and tested on the New England 10-unit 39-bus power system. By regulating the power output of the PEVs we show that (1) speed and voltage fluctuations resulting from large disturbances can be significantly reduced up to five times, and (2) the critical clearing time can be extended by 20-40%. Overall, the PEVs control strategy makes the power grid more robust.