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    Time Optimization of Seed-Mediated Gold Nanotriangle Synthesis Based on Kinetic Studies
    (Basel : MDPI, 2021) Podlesnaia, Ekaterina; Csáki, Andrea; Fritzsche, Wolfgang
    The synthesis of shape-anisotropic plasmonic nanoparticles such as gold nanotriangles is of increasing interest. These particles have a high potential for applications due to their notable optical properties. A key challenge of the synthesis is usually the low reproducibility. Even the optimized seed-based methods often lack in the synthesis yield or are labor- and time-consuming. In this work, a seed-mediated synthesis with high reproducibility is replicated in order to determine the necessary reaction time for each step. Online monitoring of the reaction mixtures by UV–VIS spectroscopy is used as a powerful tool to track the evolution of the synthesis. The kinetics of the individual stages is elucidated by real-time investigations. As a consequence, the complete synthesis could be optimized and can now be realized in a single day instead of three without any loss in the resulting sample quality.
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    A gold-nanotip optical fiber for plasmon-enhanced near-field detection
    (New York, NY : American Inst. of Physics, 2013) Uebel, P.; Bauerschmidt, S.T.; Schmidt, M.A.; Russell, P.St.J.
    A wet-chemical etching and mechanical cleaving technique is used to fabricate gold nanotips attached to tapered optical fibers. Localized surface plasmon resonances (tunable from 500 to 850 nm by varying the tip dimensions) are excited at the tip, and the signal is transmitted via the fiber to an optical analyzer, making the device a plasmon-enhanced near-field probe. A simple cavity model is used to explain the resonances observed in numerical simulations.