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Ultrafast structural and vibrational dynamics of the hydration shell around DNA

2013, Elsaesser, T., Szyc, LŁ., Yang, M.

Two-dimensional infrared spectroscopy in the frequency range of OH- and NH stretch excitations serves for a direct mapping of hydration dynamics around DNA. A moderate slowing down of structural dynamics and resonant OH stretch energy transfer is observed in the DNA water shell compared to bulk water.