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Convergence to equilibrium in energy-reaction-diffusion systems using vector-valued functional inequalities : dedicated to Peter Markowich on the occasion of his sixtieth birthday

2016, Mielke, Alexander, Mittnenzweig, Markus

We discuss how the recently developed energy-dissipation methods for reaction-diffusion systems can be generalized to the non-isothermal case. For this we use concave entropies in terms of the densities of the species and the internal energy, with the important feature, that the equilibrium densities may depend on the internal energy. Using the log-Sobolev estimate and variants for lower-order entropies as well as estimates for the entropy production of the nonlinear reactions we give two methods to estimate the relative entropy by the total entropy production, namely a somewhat restrictive convexity method, which provides explicit decay rates, and a very general, but weaker compactness method.

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Modeling of drift-diffusion systems

2006, Stephan, Holger

We derive drift-diffusion systems describing transport processes starting from free energy and equilibrium solutions by a unique method. We include several statistics, heterostructures and cross diffusion. The resulting systems of nonlinear partial differential equations conserve mass and positivity, and have a Lyapunov function (free energy). Using the inverse Hessian as mobility, non-degenerate diffusivity matrices turn out to be diagonal, or

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Weak-strong uniqueness for energy-reaction-diffusion systems

2021, Hopf, Katharina

We establish weak-strong uniqueness and stability properties of renormalised solutions to a class of energy-reaction-diffusion systems, which genuinely feature cross-diffusion effects. The systems considered are motivated by thermodynamically consistent models, and their formal entropy structure allows us to use as a key tool a suitably adjusted relative entropy method. Weak-strong uniqueness is obtained for general entropy-dissipating reactions without growth restrictions, and certain models with a non-integrable diffusive flux. The results also apply to a class of (isoenergetic) reaction-cross-diffusion systems.

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Analysis of cross-diffusion systems for fluid mixtures driven by a pressure gradient

2019, Druet, Pierre-Étienne, Jüngel, Ansgar

The convective transport in a multicomponent isothermal compressible fluid subject to the mass continuity equations is considered. The velocity is proportional to the negative pressure gradient, according to Darcy?s law, and the pressure is defined by a state equation imposed by the volume extension of the mixture. These model assumptions lead to a parabolic-hyperbolic system for the mass densities. The global-in-time existence of classical and weak solutions is proved in a bounded domain with no-penetration boundary conditions. The idea is to decompose the system into a porous-medium-type equation for the volume extension and transport equations for the modified number fractions. The existence proof is based on parabolic regularity theory, the theory of renormalized solutions, and an approximation of the velocity field.

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Global existence analysis of energy-reaction-diffusion systems

2021, Fischer, Julian, Hopf, Katharina, Kniely, Michael, Mielke, Alexander

We establish global-in-time existence results for thermodynamically consistent reaction-(cross-)diffusion systems coupled to an equation describing heat transfer. Our main interest is to model species-dependent diffusivities, while at the same time ensuring thermodynamic consistency. A key difficulty of the non-isothermal case lies in the intrinsic presence of cross-diffusion type phenomena like the Soret and the Dufour effect: due to the temperature/energy dependence of the thermodynamic equilibria, a nonvanishing temperature gradient may drive a concentration flux even in a situation with constant concentrations; likewise, a nonvanishing concentration gradient may drive a heat flux even in a case of spatially constant temperature. We use time discretisation and regularisation techniques and derive a priori estimates based on a suitable entropy and the associated entropy production. Renormalised solutions are used in cases where non-integrable diffusion fluxes or reaction terms appear.