A Stable Manganese Pincer Catalyst for the Selective Dehydrogenation of Methanol
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Date
2016-12-2
Volume
56
Issue
2
Journal
Series Titel
Book Title
Publisher
Weinheim : Wiley-VCH
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Abstract
For the first time, structurally defined manganese pincer complexes catalyze the dehydrogenation of aqueous methanol to hydrogen and carbon dioxide, which is a transformation of interest with regard to the implementation of a hydrogen and methanol economy. Excellent long-term stability was demonstrated for the Mn-PNPiPr catalyst, as a turnover of more than 20 000 was reached. In addition to methanol, other important hydrogen carriers were also successfully dehydrogenated.
Description
Keywords
dehydrogenation, homogeneous catalysis, ligand design, manganese, methanol
Citation
Andérez-Fernández, M., Vogt, L. K., Fischer, S., Zhou, W., Jiao, H., Garbe, M., et al. (2016). A Stable Manganese Pincer Catalyst for the Selective Dehydrogenation of Methanol. 56(2). https://doi.org//10.1002/anie.201610182
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License
CC BY-NC-ND 4.0 Unported